{Ln~(III)[mu5-kappa2,kappa1,kappa1,kappa1,kappa1-1,2-(CO2)2C6H4][isonicotine][H2O]}2Cu~I·X (Ln=Eu,Sm,Nd;X=ClO_4~-,Cl~-):A New Pillared-Layer Approach to Heterobimetallic 3d 4f 3D-Network Solids

Jian-Wen Cheng; Shou-Tian Zheng; En Ma

首页> 外文期刊>Inorganic Chemistry: A Research Journal that Includes Bioinorganic, Catalytic, Organometallic, Solid-State, and Synthetic Chemistry and Reaction Dynamics >{Ln~(III)[mu5-kappa2,kappa1,kappa1,kappa1,kappa1-1,2-(CO2)2C6H4][isonicotine][H2O]}2Cu~I·X (Ln=Eu,Sm,Nd;X=ClO_4~-,Cl~-):A New Pillared-Layer Approach to Heterobimetallic 3d 4f 3D-Network Solids

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{Ln~(III)[mu5-kappa2,kappa1,kappa1,kappa1,kappa1-1,2-(CO2)2C6H4][isonicotine][H2O]}2Cu~I·X (Ln=Eu,Sm,Nd;X=ClO_4~-,Cl~-):A New Pillared-Layer Approach to Heterobimetallic 3d 4f 3D-Network Solids

机译：{Ln〜（III）[mu5-kappa2，kappa1，kappa1，kappa1，kappa1-1,2-（CO2）2C6H4] [isonicotine] [H2O]} 2Cu〜I·X（Ln = Eu，Sm，Nd; X = ClO_4〜-，Cl〜-）：异双金属3d 4f 3D网络实体的一种新的分层方法

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A new series of heterometallic lanthanide(III)-copper(I) coordination polymers Ln2(bdc)2(ina)2(H2O)2Cu·X (Hina=isonicotinic acid;H2bdc=1,2-benzenedicarboxylic acid;Ln=Eu (1),Sm (2),Nd (3),X=ClO_4~-;Ln=Nd (4),X=CI~-) have been hydrothermally synthesized in the presence/absence of HClO4.Both compounds are isostructural and contained two distinct units of 2D Ln-bdc layers and linear [Cu(ina)2]-.The linear [Cu(ina)2]-complexes act as pillars and further link the Ln-bdc layers resulting in four heterometallic metal-organic frameworks,which represent the first pillared-layer 3d-4f framework with two distinct types of channels along the b and c axes.The compounds can be specified by the Schlafli symbol (4~7·63)(47·68) as a novel 3D (5,6)-connected net.Furthermore,the IR,TGA,PXRD,and UV-vis spectral and luminescent properties of 1-4 were also studied.

机译：一系列新的杂金属镧系元素（III）-铜（I）配位聚合物Ln2（bdc）2（ina）2（H2O）2Cu·X（Hina =异烟酸; H2bdc = 1,2-苯二甲酸; Ln = Eu（ 1），Sm（2），Nd（3），X = ClO_4〜-; Ln = Nd（4），X = Cl〜-）是在有或没有HClO4的情况下水热合成的。两个不同的二维Ln-bdc层和线性[Cu（ina）2]-单元。线性[Cu（ina）2]络合物充当支柱，并进一步链接Ln-bdc层，从而形成四个异金属金属有机骨架，它代表第一个柱状层3d-4f框架，沿b轴和c轴具有两种不同类型的通道。这些化合物可以用Schlafli符号（4〜7·63）（47·68）指定为一种新颖的3D （5,6）连接的网络。此外，还研究了1-4的IR，TGA，PXRD和UV-vis光谱和发光特性。

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《Inorganic Chemistry: A Research Journal that Includes Bioinorganic, Catalytic, Organometallic, Solid-State, and Synthetic Chemistry and Reaction Dynamics》 |2007年第25期|共5页
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Jian-Wen Cheng; Shou-Tian Zheng; En Ma;
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1. {Ln~(III)[mu5-kappa2,kappa1,kappa1,kappa1,kappa1-1,2-(CO2)2C6H4][isonicotine][H2O]}2Cu~I·X (Ln=Eu,Sm,Nd;X=ClO_4~-,Cl~-):A New Pillared-Layer Approach to Heterobimetallic 3d 4f 3D-Network Solids [J] . Jian-Wen Cheng, Shou-Tian Zheng, En Ma Inorganic Chemistry: A Research Journal that Includes Bioinorganic, Catalytic, Organometallic, Solid-State, and Synthetic Chemistry and Reaction Dynamics . 2007,第25期

机译：{Ln〜（III）[mu5-kappa2，kappa1，kappa1，kappa1，kappa1-1,2-（CO2）2C6H4] [isonicotine] [H2O]} 2Cu〜I·X（Ln = Eu，Sm，Nd; X = ClO_4〜-，Cl〜-）：异双金属3d 4f 3D网络实体的一种新的分层方法
2. Stereospecific assembly of chiral #LAMBDA#-Cr(III)-#DELTA#-Ln(III)-oxalato-bridged dinuclear 3d-4f complexes (Ln = Yb or Dy) and near infrared circular dichroism in the 4f->4f transitions [J] . Md. Abdus Subhan, Takayoshi Suzuki, Sumio Kaizaki Journal of the Chemical Society, Dalton Transactions. Inorganic Chemistry . 2001,第4期

机译：手性＃LAMBDA＃-Cr（III）-＃DELTA＃-Ln（III）-草酸酯桥联的双核3d-4f配合物（Ln = Yb或Dy）的立体定向组装和4f-> 4f过渡中的近红外圆二色性
3. Synthesis, Structure, and Magnetism of Heterobimetallic Trinuclear Complexes {[L(2)Co(2)Ln][X]} [Ln = Eu, X = Cl; Ln = Tb Dy, Ho, X = NO3; LH3 = (S)P[N(Me)N=CH-C6H3-2-OH-3-OMe](3)]: A 3d-4f Family of Single-Molecule Magnets [J] . Chandrasekhar V, Pandian BM, Vittal JJ, Inorganic Chemistry: A Research Journal that Includes Bioinorganic, Catalytic, Organometallic, Solid-State, and Synthetic Chemistry and Reaction Dynamics . 2009,第3期

机译：异双金属三核配合物{[L（2）Co（2）Ln] [X]}的合成，结构和磁性[Ln = Eu，X = Cl; Ln = Tb Dy，Ho，X = NO3; LH3 =（S）P [N（Me）N = CH-C6H3-2-OH-3-OMe]（3）]：3d-4f系列单分子磁体
4. {LnIIIm5-k 2, k1, k1, k1, k1-1, 2-(CO2)2C6H4isonicotineH2O}2CuIX (Ln = Eu, Sm, Nd; X = ClO4-, Cl-): A New Pillared-Layer Approach to Heterobimetallic 3d-4f 3D-Network Solids [O] . -1

机译：{LnIII M5-K 2，K1，K1，K1，K1，K1-1,2-（CO 2）2C6H4 Isonicotine H2O} 2Cuix（Ln = Eu，Sm，Nd; x = Clo4-，Cl-）：一种新的柱形层探索异常3D-4F 3D网络固体

{Ln~(III)[mu5-kappa2,kappa1,kappa1,kappa1,kappa1-1,2-(CO2)2C6H4][isonicotine][H2O]}2Cu~I·X (Ln=Eu,Sm,Nd;X=ClO_4~-,Cl~-):A New Pillared-Layer Approach to Heterobimetallic 3d 4f 3D-Network Solids

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