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Study of alinite cement hydration by impedance spectroscopy

机译:阻抗谱法研究钠水石水泥水化

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Two types of alinite cements, Mg-alinite and Zn-alinite, were synthesized using the reagent grade chemicals. Their hydration behavior was compared with ordinary Portland cement (OPC) using impedance spectroscopy (IS) and ~(29)Si nuclear magnetic resonance (NMR) spectroscopy. The bulk resistance in the IS spectra and the intensity ratio of the hydrous (Q_1 and Q_2) to anhydrous (Q_0) phases in the NMR spectra were estimated as the extent of hydration. The results obtained from both techniques were consistent each other. Mg-alinite had a comparable hydration rate to OPC and Zn-alinite exhibited faster hydration kinetics than Mg-alinite.
机译:使用试剂级化学物质合成了两种类型的硅藻土水泥:Mg-铝硅酸盐和Zn-铝硅酸盐。使用阻抗谱(IS)和〜(29)Si核磁共振(NMR)谱将它们的水化行为与普通波特兰水泥(OPC)进行了比较。将IS光谱中的体电阻和NMR光谱中的水相(Q_1和Q_2)与无水相(Q_0)的强度比估计为水合程度。从两种技术获得的结果彼此一致。镁铝硅石的水合速率与OPC相当,而锌铝硅石的水合动力学比镁铝硅石快。

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