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Photocatalytic activity of TiO 2 nanoparticles: Effect of thermal annealing under various gaseous atmospheres

机译:TiO 2纳米粒子的光催化活性:在各种气体气氛下热退火的影响

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摘要

The structure, composition and photocatalytic activity of TiO 2 nanoparticles annealed in various gas atmospheres (N 2, NH 3 and H 2) were studied in this work. The effect of treatment on crystal structure, particle size, chemical composition and optical absorbance were assessed by means of x-ray diffraction, transmission electron microscopy, x-ray photoelectron spectroscopy and diffuse optical reflectance/transmittance measurements, respectively. Photocatalytic properties of the materials were evaluated by three different methods: degradation of methyl orange in water, killing of Staphylococcus aureus bacteria and photogeneration of radicals in the presence of 3-carboxy-2,2,5,5-tetramethyl pyrrolidine-1-oxyl (PCA) marker molecules. The results indicate that the correlation between pretreatment and the photocatalytic performance depends on the photocatalytic processes and cannot be generalized.
机译:本文研究了在各种气体气氛(N 2,NH 3和H 2)下退火的TiO 2纳米颗粒的结构,组成和光催化活性。分别通过X射线衍射,透射电子显微镜,X射线光电子能谱和漫射光反射率/透射率测量来评估处理对晶体结构,粒度,化学组成和吸光度的影响。通过三种不同的方法评估了该材料的光催化性能:甲基橙在水中的降解,金黄色葡萄球菌的杀灭以及在3-羧基-2,2,5,5-四甲基吡咯烷-1-氧基存在下自由基的光生化(PCA)标记分子。结果表明,预处理与光催化性能之间的相关性取决于光催化过程,不能一概而论。

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