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SnO_2/WO_3 core-shell nanorods and their high reversible capacity as lithium-ion battery anodes

机译:SnO_2 / WO_3核壳纳米棒及其作为锂离子电池阳极的高可逆容量

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摘要

WO_3 nanorods are uniformly coated with SnO_2 nanoparticles via a facile wet-chemical route. The reversible capacity of SnO_2/WO_3 core-shell nanorods is 845.9mAhg~(-1), higher than that of bare WO_3 nanorods, SnO_2 nanostructures, and traditional theoretical results. Such behavior can be attributed to a novel mechanism by which nanostructured metallic tungsten makes extra Li_2O (from SnO_2) reversibly convert to Li ~+. This mechanism is confirmed by x-ray diffraction results. Our results open a way for enhancing the reversible capacity of alloy-type metal oxide anode materials.
机译:WO_3纳米棒通过便捷的湿化学路线均匀地涂覆有SnO_2纳米颗粒。 SnO_2 / WO_3核壳纳米棒的可逆容量为845.9mAhg〜(-1),高于裸WO_3纳米棒,SnO_2纳米结构和传统的理论结果。这种行为可归因于一种新颖的机制,通过这种机制,纳米结构的金属钨使多余的Li_2O(来自SnO_2)可逆地转化为Li〜+。 X射线衍射结果证实了该机理。我们的结果为增强合金型金属氧化物阳极材料的可逆容量开辟了道路。

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