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Thermoelectric properties of PbSe_(0.5)Te_(0.5): X (PbI_2) with endotaxial nanostructures: A promising n-type thermoelectric material

机译:具有内轴纳米结构的PbSe_(0.5)Te_(0.5):X(PbI_2)的热电性质:一种有前途的n型热电材料

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摘要

In the present investigation, we report on the thermoelectric properties of PbSe_(0.5)Te_(0.5): x (PbI_2) from room temperature to 625 K. High-resolution transmission electron micrographs of the samples reveal endotaxial nanostructures embedded in a PbSe_(0.5)Te _(0.5) matrix. The combined effect of mass fluctuation and nanostructures reduces the thermal conductivity to a great extent compared to PbTe and PbSe, without affecting the carrier mobility. As a result, a thermoelectric figure of merit with a value of 1.5 is achieved at 625 K. This value is significantly higher than that of the available state-of-the-art n-type materials.
机译:在本研究中,我们报告了从室温到625 K的PbSe_(0.5)Te_(0.5):x(PbI_2)的热电特性。样品的高分辨率透射电子显微照片揭示了嵌入PbSe_(0.5)中的内轴纳米结构Te _(0.5)矩阵。与PbTe和PbSe相比,质量波动和纳米结构的综合作用在很大程度上降低了热导率,而不会影响载流子迁移率。结果,在625 K时达到1.5的热电品质因数。该值明显高于现有的最新n型材料。

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