Self-supported spinel FeCo2O4 nanowire array: an efficient non-noble-metal catalyst for the hydrolysis of NaBH4 toward on-demand hydrogen generation

Hao Shuai; Yang Libin; Cui Liang; Lu Wenbo; Yang Yingchun; Sun Xuping; Asiri Abdullah M.

首页> 外文期刊>Nanotechnology >Self-supported spinel FeCo2O4 nanowire array: an efficient non-noble-metal catalyst for the hydrolysis of NaBH4 toward on-demand hydrogen generation

【24h】

Self-supported spinel FeCo2O4 nanowire array: an efficient non-noble-metal catalyst for the hydrolysis of NaBH4 toward on-demand hydrogen generation

机译：自支撑尖晶石FeCo2O4纳米线阵列：一种有效的非贵金属催化剂，用于NaBH4水解以按需生成氢

获取原文

获取原文并翻译 | 示例

掌桥外文数据库（机构版） >>

开具论文收录证明 >>

文献代查 >>

页面导航

摘要
著录项
相似文献
相关主题

摘要

NaBH4 has been considered as one of the most advantageous candidates for chemical hydrogen storage, but it is still a huge challenge to design efficient non-noble-metal catalysts for on-demand hydrogen generation from NaBH4 hydrolysis. In this paper, we demonstrate for the first time that a spinel FeCo2O4 nanowire array supported on carbon cloth (FeCo2O4 NA/CC) behaves as an efficient earth-abundant catalyst toward NaBH4 hydrolysis in alkaline solutions with an activation energy of 44.98 kJ mol(-1). Such FeCo2O4 NA/CC offers a hydrogen generation rate of 2551 ml min(-1) g(-1) under ambient conditions, with good stability and reusability. Its use as an ON/OFF switch for on-demand hydrogen generation is also demonstrated successfully.

机译：NaBH4被认为是化学氢存储的最有利的候选者之一，但是设计高效的非贵金属催化剂用于NaBH4水解按需生成氢仍然是一个巨大的挑战。在本文中，我们首次证明了载于碳布上的尖晶石FeCo2O4纳米线阵列（FeCo2O4 NA / CC）在碱溶液中作为NaBH4水解的有效富土催化剂，其活化能为44.98 kJ mol（- 1）。此类FeCo2O4 NA / CC在环境条件下具有2551 ml min（-1）g（-1）的氢气产生速率，具有良好的稳定性和可重复使用性。还成功证明了其用作按需生成氢气的ON / OFF开关。

著录项

来源
《Nanotechnology》 |2016年第46期|共6页
作者
Hao Shuai; Yang Libin; Cui Liang; Lu Wenbo; Yang Yingchun; Sun Xuping; Asiri Abdullah M.;
展开▼
作者单位

展开▼
收录信息
原文格式 PDF
正文语种 eng
中图分类
关键词
FeCo2O4; nanowire array; NaBH4 hydrolysis; hydrogen generation; on-demand;

机译：FeCo2O4;纳米线阵列;NaBH4水解;产氢;按需;

相似文献

外文文献
中文文献
专利

1. Self-supported spinel FeCo2O4 nanowire array: an efficient non-noble-metal catalyst for the hydrolysis of NaBH4 toward on-demand hydrogen generation [J] . Hao Shuai, Yang Libin, Cui Liang, Nanotechnology . 2016,第46期

机译：自支撑尖晶石FeCo2O4纳米线阵列：一种有效的非贵金属催化剂，用于NaBH4水解以按需生成氢
2. Monolithically integrated CoP nanowire array: An on/off switch for effective on-demand hydrogen generation via hydrolysis of NaBH4 and NH3BH3 [J] . Liang Cui, Yuanhong Xu, Li Niu, 纳米研究（英文版） . 2017,第002期

机译：单片集成CoP纳米线阵列：通过NaBH4和NH3BH3水解有效产生按需氢的开/关开关
3. Self-supported CoP nanosheet arrays: a non-precious metal catalyst for efficient hydrogen generation from alkaline NaBH4 solution [J] . Liu Tingting, Wang Kunyang, Du Gu, Journal of Materials Chemistry, A. Materials for energy and sustainability . 2016,第34期

机译：自支撑的CoP纳米片阵列：一种非贵金属催化剂，用于从碱性NaBH4溶液中高效产生氢气
4. Catalytic Hydrolysis of NaBH4 with Ni-Co-B Catalysts for In-situ Hydrogen Supply of Proton Exchange Membrane Fuel Cell [C] . Chuan Wu, Ying Bai, Feng Wu, 6th international conference on environmental catalysis : Abstract book . 2010

机译：Ni-Co-B催化剂催化的NaBH4水解为质子交换膜燃料电池原位供氢
5. Stacked Core-Shell & Self-Supported Nanorod Array Electrocatalysts for PEM Fuel Cells [D] . Yurtsever, Fatma Merve. 2018

机译：堆叠芯壳和自支撑纳米棒阵列电催化剂用于PEM燃料电池
6. Self-Supported Ni(P O)x·MoOx Nanowire Array on Nickel Foam as an Efficient and Durable Electrocatalyst for Alkaline Hydrogen Evolution [O] . Wei Hua, Huanyan Liu, Jian-Gan Wang, 2017

机译：镍泡沫上的自支撑Ni（PO）x·MoOx纳米线阵列作为碱性氢释放的高效耐用电催化剂
7. Efficient Hydrogen Generation from the NaBH4 Hydrolysis by Cobalt-Based Catalysts: Positive Roles of Sulfur-Containing Salts [O] . -1

机译：基于钴的催化剂的NaBH4水解产生的高效氢：含硫盐的阳性作用

Self-supported spinel FeCo2O4 nanowire array: an efficient non-noble-metal catalyst for the hydrolysis of NaBH4 toward on-demand hydrogen generation

摘要

著录项

相似文献

相关主题

期刊订阅