Synthesis of quinolines through copper-catalyzed intermolecular cyclization reaction from anilines and terminal acetylene esters

Zheng Zhilei; Deng Guobo; Liang Yun

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Synthesis of quinolines through copper-catalyzed intermolecular cyclization reaction from anilines and terminal acetylene esters

机译：铜催化苯胺和末端乙炔酯的分子间环化反应合成喹啉

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A simple and convenient copper-catalyzed intermolecular cyclization reaction for the synthesis of quinolines from anilines and terminal acetylene esters has been developed. This methodology constructs the C-N and C-C bonds successively via a cascade process, and provides the desired products in moderate to good yields.

机译：开发了一种简单方便的铜催化分子间环化反应，用于由苯胺和末端乙炔酯合成喹啉。该方法学通过级联方法连续构建C-N和C-C键，并以中等至良好的产率提供所需的产物。

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《RSC Advances》 |2016年第105期|共4页
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Zheng Zhilei; Deng Guobo; Liang Yun;
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1. Synthesis of quinolines through copper-catalyzed intermolecular cyclization reaction from anilines and terminal acetylene esters [J] . Zheng Zhilei, Deng Guobo, Liang Yun RSC Advances . 2016,第105期

机译：铜催化苯胺和末端乙炔酯的分子间环化反应合成喹啉
2. Aerobic synthesis of substituted quinoline from aldehyde and aniline: Copper-catalyzed intermolecular C-H active and C-C formative cyclization [J] . Yan R., Liu X., Pan C., Organic letters . 2013,第18期

机译：由醛和苯胺有氧合成取代喹啉：铜催化的分子间C-H活性和C-C形成环化
3. A copper-catalyzed reaction between terminal alkynes, acetylenic esters, and oxiranes: efficient synthesis of 2H-pyran-4-carboxylate [J] . Monatshefte fur Chemie . 2020,第1期

机译：烷基苯，乙炔酯和草酸之间的铜催化反应：高效合成2H-吡喃-4-羧酸盐
4. Copper-Catalyzed Synthesis of Esters from Ketones by Addition-Elimination Reaction [C] . Yuji Nakatani, Yuichiro Koizumi, Shinichi Saito Symposium on Organometallic Chemistry . 2007

机译：通过添加 - 消除反应铜催化的合成酮酯的酯
5. I. Catalysis of Intra- and Intermolecular Schmidt Reactions. II. Copper-Catalyzed Oxaziridine-Mediated C-H Bond Oxidation. III. Synthesis and Cytotoxic Evaluation of Withalongolide A Analogues. [D] . Motiwala, Hashim F. 2014

机译：I.分子内和分子间施密特反应的催化。二。铜催化的恶唑烷介导的C-H键氧化。三， Withalongolide A类似物的合成和细胞毒性评估。
6. Synthesis of Substituted Quinolines by the Electrophilic Cyclization of N-(2-Alkynyl)anilines [O] . Xiaoxia Zhang, Tuanli Yao, Marino A. Campo, -1

机译：通过N-（2-炔基）苯胺的亲电环化合成取代的喹啉
7. Correction to Direct Synthesis of 4-Quinolones via Copper-Catalyzed Intermolecular Cyclization of Anilines and Alkynes [O] . Xuefeng Xu, Xu Zhang 2018

机译：通过铜催化的苯胺和炔烃直接合成4-喹诺酮的校正

Synthesis of quinolines through copper-catalyzed intermolecular cyclization reaction from anilines and terminal acetylene esters

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