Selective palladium-catalyzed carbonylative synthesis of aurones with formic acid as the CO source

Qi Xinxin; Li Rui; Wu Xiao-Feng

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Selective palladium-catalyzed carbonylative synthesis of aurones with formic acid as the CO source

机译：以甲酸为CO源的钯的选择性钯催化羰基合成

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A general and practical strategy has been developed to prepare aurone derivatives. In the presence of the palladium catalyst, 2-iodophenol and terminal alkynes were reacted by using formic acid as the CO source with acetic anhydride as the additive. A variety of aurones were obtained in moderate to good yields. Notably, this is first report on carbonylative synthesis of aurones with formic acid as the CO source.

机译：已经开发了制备金酮衍生物的通用和实用策略。在钯催化剂的存在下，通过使用甲酸作为CO源和乙酸酐作为添加剂，使2-碘苯酚和末端炔烃反应。以中等至良好的产率获得了各种金红。值得注意的是，这是关于以甲酸为CO源的金酮羰基合成的首次报道。

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《RSC Advances》 |2016年第67期|共4页
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Qi Xinxin; Li Rui; Wu Xiao-Feng;
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1. Selective palladium-catalyzed carbonylative synthesis of aurones with formic acid as the CO source [J] . Qi Xinxin, Li Rui, Wu Xiao-Feng RSC Advances . 2016,第67期

机译：以甲酸为CO源的钯的选择性钯催化羰基合成
2. Palladium-Catalyzed Carbonylative Transformation of Organic Halides with Formic Acid as the Coupling Partner and CO Source: Synthesis of Carboxylic Acids [J] . Wu Fu-Peng, Peng Jin-Bao, Qi Xinxin, The Journal of Organic Chemistry . 2017,第18期

机译：用甲酸作为偶联合作伙伴和CO来源的钯催化的有机卤化物的羰基化转化：合成羧酸
3. Palladium-catalyzed carbonylative Sonogashira cross-coupling for the synthesis of alkynones with formic acid as the CO source [J] . Lyu Xue, Sun Guanglong, Zhou Yang, Monatshefte fur Chemie . 2019,第2期

机译：钯催化的羰基化Sonogashira交叉偶联用于合成炔烃与甲酸作为CO源
4. Palladium-Catalyzed Selective Reductive Ring Opening Reaction of Vinylsulfonyloxiranes with Formic Acid [C] . Masaharu Iwakura, Morihisa Saito, Isao Shimizu Symposium on Organometallic Chemistry . 2004

机译：乙烯基磺酰氧基乙烯基与甲酸的钯催化的选择性还原环开启反应
5. Exploration of alpha-Diazocarbonyl Compounds for Transition-Metal Catalyzed Carbon-Carbon Bond Formations. Development of Palladium-Catalyzed Stereoselective Synthesis of Trisubstituted Alkenes and the Synthesis of Quaternary alpha,alpha-Heterodiaryl Carboxylic Acids by Rhodium-Catalyzed Multi-Component Coupling Reactions. [D] . Tsoi, Yuk Tai. 2012

机译：探索用于过渡金属催化的碳-碳键形成的α-重氮羰基化合物。铑催化的多组分偶合反应在钯催化的立体选择性合成三取代的烯烃上的发展和季铵的α，α-杂二芳基羧酸的合成。
6. Palladium-Catalyzed Synthesis of Aldehydes from Aryl Iodides and Formic acid with Propylphosphonic Anhydride as the Activator [O] . Xiao-Feng Wu -1

机译：丙膦酸酐为活化剂钯催化催化芳基碘化物和甲酸合成醛
7. Inside Cover: Palladium-Catalyzed One-Pot Carbonylative Sonogashira Reaction Employing Formic acid as the CO Source (Chem. Asian J. 9/2015) [O] . Xinxin Qi, Li-Bing Jiang, Chong-Liang Li, 2015

机译：内盖：钯催化的单罐羰基化Sonogashira反应，含有甲酸作为CO源（Chem。亚洲J. 9/2015）

Selective palladium-catalyzed carbonylative synthesis of aurones with formic acid as the CO source

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