Structural isomers of iron(III) N-methyl diethanolaminate as sol-gel precursors for iron-based oxide nanomaterials

Mishra Shashank; Jeanneau Erwann; Rolland Marc; Daniele Stephane

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Structural isomers of iron(III) N-methyl diethanolaminate as sol-gel precursors for iron-based oxide nanomaterials

机译：N-甲基二乙醇铁（III）的结构异构体，作为铁基氧化物纳米材料的溶胶-凝胶前体

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A new homoleptic iron(III) complex, [Fe-4(mdea)(6)]center dot 6CHCl(3) (mdeaH(2) = N-methyl diethanolamine), isolated in star-or chair-shaped isomeric forms, was evaluated and compared with other homoleptic iron(III) aminoalkoxides for different sol-gel parameters to stabilize nanosized colloidal suspensions, and to elaborate magnetic Fe2O3 and BiFeO3 nanoparticles as well as thin films by spin coating.

机译：一个新的均铁铁（III）络合物，[Fe-4（mdea）（6）]中心点6CHCl（3）（mdeaH（2）= N-甲基二乙醇胺），以星形或椅子形异构形式分离。评估并与其他均铁性铁（III）氨基醇盐进行比较，以求出不同的溶胶-凝胶参数，以稳定纳米级胶体悬浮液，并通过旋涂精制磁性Fe2O3和BiFeO3纳米颗粒以及薄膜。

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《RSC Advances》 |2016年第3期|共6页
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Mishra Shashank; Jeanneau Erwann; Rolland Marc; Daniele Stephane;
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1. Structural isomers of iron(III) N-methyl diethanolaminate as sol-gel precursors for iron-based oxide nanomaterials [J] . Mishra Shashank, Jeanneau Erwann, Rolland Marc, RSC Advances . 2016,第3期

机译：N-甲基二乙醇铁（III）的结构异构体，作为铁基氧化物纳米材料的溶胶-凝胶前体
2. Silicon oxide in an iron(III) oxide matrix: the sol-gel synthesis and characterization of Fe-Si mixed oxide nanocomposites that contain iron oxide as the major phase [J] . Clapsaddle BJ., Gash AE., Satcher JH., Journal of Non-Crystalline Solids: A Journal Devoted to Oxide, Halide, Chalcogenide and Metallic Glasses, Amorphous Semiconductors, Non-Crystalline Films, Glass-Ceramics and Glassy Composites . 2003,第1a3期

机译：氧化铁（III）基质中的氧化硅：以氧化铁为主要相的Fe-Si混合氧化物纳米复合材料的溶胶-凝胶合成和表征
3. New sol-gel precursors for binary oxides of antimony, Sb2O3 (senarmonite) and α-Sb2O4: synthesis and characterization of some ketoximate modified antimony(III) alkoxides [J] . Neelam Yadav, Meena Nagar, Rakesh Bohra Journal of Sol-Gel Science and Technology . 2010,第1期

机译：锑，Sb2O3（亚硒酸钠）和α-Sb2O4的二元氧化物的新型溶胶-凝胶前体：某些酮肟酸修饰的锑（III）醇盐的合成和表征
4. Single-source precursor and homometal approaches to the sol-gel synthesis of iron and titanium oxides [C] . P. H. C. Camargo, G. G. Nunes, D. J. Evans, International Conference on Surface and Colloid Science . 2004

机译：单源前体和溶胶 - 凝胶合成铁和钛氧化物的均等方法
5. Synthesis of p-iron(III) oxide, n-iron(III) oxide, and carbon-modified-n-titanium dioxide and their application in self-driven photoelectrochemical cells: p-iron(III) oxide/n-iron(III) oxide, p-iron(III) oxide/carbon-modified-n-titanium dioxide, and p-gallium indium phosphide/carbon-modified-n-titanium dioxide for direct water photoelectrolysis [D] . Ingler, William B., Jr. 2005

机译：对氧化铁（III），正氧化铁（III）和碳改性的正二氧化钛的合成及其在自驱动光电化学电池中的应用：对氧化铁（III）/正铁（III））氧化物，用于水直接电解的对-氧化铁（III）/碳改性的正二氧化钛和对镓磷化铟/碳改性的正二氧化钛
6. Recyclable nanoscale zero-valent iron-based magnetic polydopamine coated nanomaterials for the adsorption and removal of phenanthrene and anthracene [O] . Jing Li, Qingxiang Zhou, Yongli Liu, 2017

机译：可回收的纳米级零价铁基磁性聚多巴胺涂层纳米材料用于吸附和去除菲和蒽
7. The Effect of Precursors Concentration on the Structure and Micromagnetic Properties of Ultrafine Iron Oxides Obtained by Sol-Gel Route [O] . V. Kotsyubynsky, A. Hrubiak, L. Mohnatska, 2016

机译：前体浓度对溶胶 - 凝胶途径获得超细氧化铁结构和微磁性能的影响

Structural isomers of iron(III) N-methyl diethanolaminate as sol-gel precursors for iron-based oxide nanomaterials

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