Copper-catalyzed tandem reaction in ionic liquid: an efficient reusable catalyst and solvent media for the synthesis of fused poly hetero cyclic compounds

Naidu Shivaji; Reddy Sabbasani Rajasekhara

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Copper-catalyzed tandem reaction in ionic liquid: an efficient reusable catalyst and solvent media for the synthesis of fused poly hetero cyclic compounds

机译：离子液体中的铜催化串联反应：一种有效的可重复使用的催化剂和溶剂介质，用于合成稠合多杂环化合物

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Herein we report a copper catalyzed tandem reaction for the synthesis of therapeutically important pyrrolo-/pyrido[2,1-b] benzo[d][1,3] oxazin-1-ones from 2-aminobezyl alcohols using alkynoic acids under ligand and base free conditions in the presence of a green solvent medium [bmim]OTf. The catalyst and solvent were successfully recycled and reused.

机译：在这里，我们报道了铜催化串联反应，用于在配体和配体下使用炔酸从2-氨基苄醇合成具有重要治疗意义的吡咯并//吡啶并[2,1-b]苯并[d] [1,3]恶嗪-1-酮。在绿色溶剂介质[bmim] OTf存在下的无碱条件。催化剂和溶剂已成功回收和再利用。

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《RSC Advances》 |2016年第67期|共5页
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Naidu Shivaji; Reddy Sabbasani Rajasekhara;
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1. Copper-catalyzed tandem reaction in ionic liquid: an efficient reusable catalyst and solvent media for the synthesis of fused poly hetero cyclic compounds [J] . Naidu Shivaji, Reddy Sabbasani Rajasekhara RSC Advances . 2016,第67期

机译：离子液体中的铜催化串联反应：一种有效的可重复使用的催化剂和溶剂介质，用于合成稠合多杂环化合物
2. Palladium supported on poly (ionic liquid) entrapped magnetic nanoparticles as a highly efficient and reusable catalyst for the solvent-free Heck reaction [J] . Liu Wendong, Wang Dongfang, Duan Yajing, Tetrahedron letters: The International Journal for the Rapid Publication of Preliminary Communications in Organic Chemistry . 2015,第14期

机译：载于聚（离子液体）的磁性纳米颗粒上的钯作为高效的可重复使用的催化剂，可用于无溶剂的Heck反应
3. 4-VP]-Fe 3O 4 supported Br?nsted acid ionic liquid and its application as a highly efficient heterogeneous and reusable nanocatalyst in the Biginelli reaction under solvent-free conditions]]> [J] . Mohammad Ali Karimi Zarchi, Zeinab Hamidi Reaction kinetics,mechanisms and catalysis . 2018,第2期

机译：<！[CDATA [合成[P <下标> 4 -VP] -fe <下标> 3 O <下标> 4 支持的BR？NSTED酸离子液及其应用在无溶剂条件下，在Biginelli反应中具有高效的异质和可重复使用的纳米催化剂]]]>
4. Reusable Reaction Systems Derived from Fluorous Solvents or Ionic Liquids and Catalysts [C] . Tomoya Kitazume 220th National Meeting of the American Chemical Society (ACS), Aug 20-24, 2000, Washington, D.C. . 2000

机译：源自氟溶剂或离子液体和催化剂的可重复使用的反应系统
5. Polar ionic media and stabilized charged species in organic synthesis: Ionic liquids derived from a biorenewable source, D-fructose, as a possible alternative to conventional organic reaction solvents. [D] . Okello, Maurice O. 2004

机译：有机合成中的极性离子介质和稳定的带电物种：来源于生物可再生来源D-果糖的离子液体，可以作为常规有机反应溶剂的替代方法。
6. Room Temperature Ionic Liquids in Asymmetric Hetero-Ene Type Reactions: Improving Organocatalyst Performance at Lower Temperatures [O] . Fabricio R. Bisogno, Rosario Fernández, Jose María Lassaletta, 2021

机译：房间温度离子液体在不对称异质型反应：改善较低温度下的有机催化剂性能
7. Lanthanide-mediated organic synthesis : lanthanide(III) compounds as Lewis acid catalysts and cerium(IV) compounds as reagents for reactions in ionic liquids [O] . Deleersnyder Karen 2007

机译：镧系元素介导的有机合成：镧系元素（III）作为路易斯酸催化剂，铈（IV）类化合物作为离子液体中反应的试剂

Copper-catalyzed tandem reaction in ionic liquid: an efficient reusable catalyst and solvent media for the synthesis of fused poly hetero cyclic compounds

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