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Preparation of organic mechanochromic fluorophores with simple structures and promising mechanochromic luminescence properties

机译:具有简单结构和有希望的机械变色发光特性的有机机械变色荧光团的制备

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摘要

Organic mechanochromic fluorescent materials have attracted increasing interest over the last few years. However, organic mechanochromic fluorophores reported so far usually have complicated structures and require multi-step synthesis. In this paper, a simple method to design and synthesize organic mechanochromic fluorophores with simple structures and promising mechanochromic luminescence properties is reported. Based on this method, a broad range of pyrene-based phosphonium materials with promising mechanochromic luminescence have been developed. Among all pyrene-based mechanochromic materials reported so far, tributyl(pyren-1-ylmethyl)phosphonium fluorophore 1.PF6 reported in this paper is the smallest pyrene-based mechanochromic fluorophore with the longest emission wavelength shift. The method reported in this study has shown great potential for the rapid construction of mechanochromic materials and opened a new avenue to develop novel mechanochromic materials.
机译:在过去的几年中,有机机械变色荧光材料引起了越来越多的兴趣。然而,迄今为止报道的有机机械变色荧光团通常具有复杂的结构并且需要多步合成。本文报道了一种简单的方法来设计和合成具有简单结构和有希望的机械变色发光特性的有机机械变色荧光团。基于该方法,已经开发了具有前景的机械变色发光的多种of基-材料。在迄今为止报道的所有pyr基机械变色材料中,本文报道的三丁基(吡喃-1-基甲基)phosph荧光团1.PF6是最小的pyr基机械变色荧光团,具有最长的发射波长漂移。本研究报道的方法显示了快速构建机械变色材料的巨大潜力,并开辟了开发新型机械变色材料的新途径。

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