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Solid-state, individual dispersion of single-walled carbon nanotubes in ionic liquid-derived polymers and its impact on thermoelectric properties

机译:固态单壁碳纳米管在离子液体衍生的聚合物中的固态分散及其对热电性能的影响

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摘要

The structure of carbon nanotubes and their electronic interaction with a matrix are important for extracting the unprecedented electronic properties, which have yet to be explored. Here we investigate the dispersibility of single-walled carbon nanotubes (SWNTs) in ionic liquid-derived polymers (PILs), revealed by cross-sectional transmission electron microscopy, infrared optical spectroscopy, and Raman spectroscopy. Surprisingly, SWNTs studied here are highly dispersed, at least down to 7.5 nm-fibres, in a trimethylammonium-suspended PILs. Based on this discovery, we found that the well-dispersed and almost fully dispersed SWNTs in PILs are responsible for the enhanced thermoelectric properties, a future energy harvesting technique.
机译:碳纳米管的结构及其与基质的电子相互作用对于提取前所未有的电子性能非常重要,这有待探索。在这里,我们通过截面透射电子显微镜,红外光谱和拉曼光谱揭示了单壁碳纳米管(SWNT)在离子液体衍生的聚合物(PIL)中的分散性。令人惊讶的是,本文研究的单壁碳纳米管在三甲基铵悬浮的PIL中高度分散,至少低至7.5 nm纤维。基于此发现,我们发现PIL中分散良好且几乎完全分散的单壁碳纳米管有助于增强热电性能,这是一种未来的能量收集技术。

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