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Preheating-assisted deposition of solution-processed perovskite layer for an efficiency-improved inverted planar composite heterojunction solar cell

机译:效率提高的倒置平面复合异质结太阳能电池固溶体钙钛矿层的预热辅助沉积

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摘要

Planar heterojunction perovskite solar cells have received a lot of attention due to their great potential, such as low-cost and rapidly improving performance. However, the poor fill surface coverage and numerous pinholes usually exist in the organic-inorganic hybrid perovskite layers, leading to undesirable electron-hole recombination. Herein, inverted cell structures based on NiOx/PCBM interfacial materials have been studied. A simple preheating method facilitates the formation of a relatively continuous and compact layer of well-crystallized CH3NH3PbI3-xClx perovskite by a one-step solution process, which can minimize film defects and thus improve the charge extraction dissociation and transport abilities at the interface. As a result, synchronized improvements in photovoltage (V-oc), photocurrent (J(sc)) and fill factor (FF) lead to similar to 25% enhanced power conversion efficiency (PCE), compared to solar cells using conventional perovskite films. Our study highlights a simple and effective method to improve the perovskite film quality and the photovoltaic performance of inverted perovskite solar cells.
机译:平面异质结钙钛矿太阳能电池由于其巨大的潜力而备受关注,例如低成本和性能快速提高。然而,在无机-无机杂化钙钛矿层中通常存在较差的填充表面覆盖率和许多针孔,导致不希望的电子-空穴复合。在此,已经研究了基于NiOx / PCBM界面材料的倒置电池结构。一种简单的预热方法有助于通过一步溶液法形成相对连续且致密的结晶良好的CH3NH3PbI3-xClx钙钛矿层,该过程可以最大程度地减少膜缺陷,从而改善界面处的电荷提取解离和传输能力。结果,与使用常规钙钛矿膜的太阳能电池相比,光电压(V-oc),光电流(J(sc))和填充因数(FF)的同步改善导致功率转换效率(PCE)提高了25%。我们的研究突出了一种简单有效的方法来提高钙钛矿薄膜质量和倒置钙钛矿太阳能电池的光伏性能。

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