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Intensive green emission of ZnAl_(2)O_(4):Mn~(2+) under vacuum ultraviolet and low-voltage cathode ray excitation

机译:真空紫外和低压阴极射线激发下ZnAl_(2)O_(4):Mn〜(2+)的密集绿色发射

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摘要

A series of Zn_(1-x)Mn_(x)Al_(2)O_(4) (x velence 0.001 approx 0.08) phosphors were synthesized by a traditional solid-state reaction route. Their photoluminescence under vacuum ultraviolet (VUV, energy E > 50000 cm~(-1), wavelength lambda < 200 nm) and cathodoluminescence under low-voltage electron beam excitation were evaluated. The luminescence decays were also measured. The intense green emission was observed with a peak at about 510 nm upon 172/147 nm excitation. The luminescence of optimum phosphor Zn_(0.99)Mn_(0.01)Al_(2)O_(4) (ZAM) was compared with that of commercial green phosphor Zn_(2)SiO_(4):Mn~(2+) (ZSM). The maximum emission intensity of ZAM is larger than that of ZSM under 172/147 nm and low-voltage electron beam excitation. The values of chromaticity coordinates reveal the phosphors can evidently enlarge the tricolor gamut. The results show that the ZnAl_(2)O_(4):Mn~(2+) phosphors may be considered as candidates for Hg-free lamps, plasma flat backlights, and field emission backlights for liquid crystal displays.
机译:通过传统的固态反应路线合成了一系列的Zn_(1-x)Mn_(x)Al_(2)O_(4)(x速度0.001约0.08)荧光粉。评估了它们在真空紫外线下的光致发光(VUV,能量E> 50000 cm〜(-1),波长λ<200 nm)和低压电子束激发下的阴极发光。还测量了发光衰减。在172/147 nm激发下,观察到强烈的绿色发射,在约510 nm处有一个峰。比较了最佳荧光粉Zn_(0.99)Mn_(0.01)Al_(2)O_(4)(ZAM)的发光与商用绿色荧光粉Zn_(2)SiO_(4):Mn〜(2+)(ZSM)的发光。在172/147 nm和低压电子束激发下,ZAM的最大发射强度大于ZSM。色度坐标值表明磷光体可以明显扩大三色域。结果表明,ZnAl_(2)O_(4):Mn〜(2+)荧光粉可被视为无汞灯,等离子平板背光和液晶显示器的场发射背光的候选材料。

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