A Simple Route to Keto-Substituted (eta(5)-Cyclohexadienyl)Mn(CO)(3) Complexes Using Organomanganese Transmetalation: Structural and Theoretical Characterizations

Eloi A; Rose-Munch F; Rose E; Chavarot-Kerlidou M; Gerard H

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A Simple Route to Keto-Substituted (eta(5)-Cyclohexadienyl)Mn(CO)(3) Complexes Using Organomanganese Transmetalation: Structural and Theoretical Characterizations

机译：一种简单的途径，使用有机锰金属过渡金属取代酮（（（5）-环己二烯基）Mn（CO）（3）配合物：结构和理论表征

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Efficient synthesis of keto-substituted (eta(5)-cyclohexadienyl)Mn(CO)(3) complexes is achieved by, organomanganese transmetalation catalyzed by Fe(acac)(3). Density junctional theory (DFT) calculations highlight the influence of the keto group position on the strength of conjugation between the RCO function and the cyclohexadienyl ring and shed light on the regioselectivity of nucleophilic attacks on such complexes.

机译：有效的合成酮取代的（eta（5）-环己二烯基）Mn（CO）（3）配合物是通过Fe（acac）（3）催化的有机锰金属转移实现的。密度连接理论（DFT）的计算突显了酮基位置对RCO功能与环己二烯基环之间共轭强度的影响，并阐明了此类配合物的亲核进攻的区域选择性。

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《Organometallics》 |2009年第3期|共4页
作者
Eloi A; Rose-Munch F; Rose E; Chavarot-Kerlidou M; Gerard H;
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正文语种 eng
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PLANAR CHIRALITY; LITHIATION/ELECTROPHILIC QUENCH; GRIGNARD-REAGENTS; REACTIVITY; ARENE; (ETA(6)-ARENE)TRICARBONYLCHROMIUM; REGIOSELECTIVITY; RESOLUTION; CHEMISTRY; CATIONS;

机译：平面手性;锂化/亲电猝灭;格氏试剂;反应性;芳烃;（ETA（6）-芳烃）三羰基铬;区域选择性;拆分;化学;阳离子;

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1. A Simple Route to Keto-Substituted (eta(5)-Cyclohexadienyl)Mn(CO)(3) Complexes Using Organomanganese Transmetalation: Structural and Theoretical Characterizations [J] . Eloi A, Rose-Munch F, Rose E, Organometallics . 2009,第3期

机译：一种简单的途径，使用有机锰金属过渡金属取代酮（（（5）-环己二烯基）Mn（CO）（3）配合物：结构和理论表征
2. Unprecedented (eta(5)-formylcyclohexadienyl)Mn(CO)(3) complexes: Synthesis, structural and theoretical characterizations, and resolution of the planar chirality [J] . Jacques B, Eloi A, Chavarot-Keridou M, Organometallics . 2008,第11期

机译：前所未有的（eta（5）-甲酰基环己二烯基）Mn（CO）（3）配合物：合成，结构和理论表征，以及平面手性的拆分
3. Two octahedral sigma-borane metal (Mn-I and Ru-II) complexes containing a tripod kappa N-3,H,H-ligand: Synthesis, structural characterization, and theoretical topological study of the charge density [J] . Van der Maelen Juan F., Brugos Javier, Garcia-Alvarez Pablo, Journal of Molecular Structure . 2020,第期

机译：含有三脚架Kappa N-3，H，H-Ligand：合成，结构表征和电荷密度的理论拓扑研究的两种八叶二甲基硼烷金属（Mn-1和Ru-II）配合物
4. Synthesis of Aryliron Complexes by Palladium-Catalyzed Transmetalation between CpFe(CO)2I and Arylmetal Reagents [C] . Shigeo Yasuda, Yoshihiro Asada, Bideki Yorimitsu Symposium on Organometallic Chemistry . 2008

机译：通过CPFE（CO）2I和芳基 - 试剂之间的钯催化透射率来合成芳基络合物
5. Reductive activation of arene, cyclohexadienyl and tropylium complexes of the early transition metals: Mechanisms and reactivities. [D] . Shao, Li. 2001

机译：早期过渡金属的芳烃，环己二烯基和对yl鎓络合物的还原活化：机理和反应性。
6. Synthesis and Structural Characterization of a Series of Mn(III)-OR Complexes Including a Water-Soluble Mn(III)-OH that Promotes Aerobic Hydrogen Atom Transfer [O] . Michael K. Coggins, Lisa M. Brines, Julie A. Kovacs -1

机译：一系列Mn（III）-OR配合物的合成和结构表征包括促进需氧氢原子转移的水溶性Mn（III）-OH
7. Two octahedral σ-borane metal (MnI and RuII) complexes containing a tripod κ3N,H,H-ligand: Synthesis, structural characterization, and theoretical topological study of the charge density [O] . Juan F. Van der Maelen, Javier Brugos, Pablo García-Álvarez, 2020

机译：含有三脚架κ3n，h，h-ligand：合成，结构表征和电荷密度的理论拓扑研究的两个八面乳碱和ruii）配合物

A Simple Route to Keto-Substituted (eta(5)-Cyclohexadienyl)Mn(CO)(3) Complexes Using Organomanganese Transmetalation: Structural and Theoretical Characterizations

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