A Monomeric Perfluoroalkyl Iridium(III) Amido Complex with an Ir = N Double Bond and Its Reactions To Activate sp(3) Carbon-Hydrogen Bonds at Room Temperature

Yuan J; Hughes RP; Rheingold AL

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A Monomeric Perfluoroalkyl Iridium(III) Amido Complex with an Ir = N Double Bond and Its Reactions To Activate sp(3) Carbon-Hydrogen Bonds at Room Temperature

机译：具有Ir = N双键的单体全氟烷基铱（III）酰胺配合物及其在室温下活化sp（3）碳氢键的反应

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A simple iridium amido complex has been prepared and shown to contain an unambiguous Ir=N double bond, using X-ray crystallography and DFT calculations. The compound exhibits remarkable reactivity by activating the allylic C-H bonds, of terminal alkenes at room temperature, liberating (BuNH2)-Bu-t and forming eta(3)-allylic complexes of iridium.

机译：使用X射线晶体学和DFT计算，已经制备了一种简单的铱酰胺基络合物，并显示含有明确的Ir = N双键。该化合物通过在室温下活化末端烯烃的烯丙基C-H键，释放（BuNH2）-Bu-t并形成铱的eta（3）-烯丙基络合物，表现出显着的反应性。

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《Organometallics》 |2009年第16期|共3页
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Yuan J; Hughes RP; Rheingold AL;
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1. A Monomeric Perfluoroalkyl Iridium(III) Amido Complex with an Ir = N Double Bond and Its Reactions To Activate sp(3) Carbon-Hydrogen Bonds at Room Temperature [J] . Yuan J, Hughes RP, Rheingold AL Organometallics . 2009,第16期

机译：具有Ir = N双键的单体全氟烷基铱（III）酰胺配合物及其在室温下活化sp（3）碳氢键的反应
2. Activation of Small Molecules by the Metal Amido Bond of Rhodium(III) and Iridium(III) (eta(5)-C5Me5)M-Aminopyridinate Complexes [J] . Zamorano Ana, Rendon Nuria, Lopez-Serrano Joaquin, Inorganic Chemistry: A Research Journal that Includes Bioinorganic, Catalytic, Organometallic, Solid-State, and Synthetic Chemistry and Reaction Dynamics . 2018,第1期

机译：通过铑（III）和铱（III）（III）（ETA（5）-C5ME5）M-氨基吡啶复合物的金属酰胺键活化
3. Cooperative bimetallic effects on new iridium(III) pyrazolate complexes: Hydrogen-hydrogen, carbon-hydrogen, and carbon-chlorine bond activations [J] . Sola E., Torres F., Elduque A., Organometallics . 1998,第4期

机译：新型双吡唑鎓铱（III）配合物的双金属协同作用：氢-氢，碳-氢和碳-氯键活化
4. C-H Bond Activation by Iridium and Rhodium Complexes: Catalytic Hydrogen-Deuterium Exchange and C-C Bond-Forming Reactions [C] . Steven R. Klei, Klan L. Tan, Jeffrey T. Golden, American Chemical Society National Meeting . 2004

机译：铱和铑配合物的C-H键活化：催化氢 - 氘交换和C-C键形成反应
5. Carbon-hydrogen bond activation by iridium(III) complexes. [D] . Chen, Junyi. 2001

机译：铱（III）配合物激活碳氢键。
6. Titanium Imido Complexes via Displacement of –SiMe3 and C–H Bond Activation in a Ti(III) Amido Complex Promoted by a Cyclic (Alkyl)(Amino) Carbene (cAAC) [O] . Qing Ye, Micah S. Ziegler, K. V. Lakshmi, -1

机译：钛亚氨基配合物通过环（烷基）（氨基）碳（cAAC）促进的Ti（III）氨基配合物中的-SiMe3和CH键的置换活化
7. Facile Oxygen Atom Insertion into Unactivated C(sp3)-C(sp2) Single Bonds in Reactions of Iridium(III) Complexes with O2 [O] . Cristóbal, Crispín, Álvarez, Eleuterio, Paneque, Margarita, 2013

机译：铱（III）配合物与氧气反应中容易的氧原子插入未激活的C（sp3）-C（sp2）单键
8. Oxidative Addition of Soluble Iridium and Rhodium Complexes to Carbon-Hydrogen Bonds in Alkanes [R] . Janowicz, A. H., Kovac, C. A., Periana-Pillai, R. A., 1983

机译：可溶性铱和铑配合物氧化加成烷烃中的碳氢键

A Monomeric Perfluoroalkyl Iridium(III) Amido Complex with an Ir = N Double Bond and Its Reactions To Activate sp(3) Carbon-Hydrogen Bonds at Room Temperature

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