Unprecedented reactivity of Iridium(I) secondary phosphine oxide complexes: Formation of P-coordinated phosphinate complexes by P-aryl bond cleavage

Liniger M.; Gschwend B.; Neuburger M.; Schaffner S.; Pfaltz A.

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Unprecedented reactivity of Iridium(I) secondary phosphine oxide complexes: Formation of P-coordinated phosphinate complexes by P-aryl bond cleavage

机译：铱（I）次膦氧化物配合物的前所未有的反应性：通过P-芳基键的裂解形成P配位的次膦酸酯配合物

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Aryl-iridium(III) hydride complexes with a P-coordinated phosphinate were formed from [Ir(cod)Cl]_2 and secondary phosphine oxide-oxazoline ligands under basic conditions. The structure of these complexes, whose formation involved C-P cleavage, was assigned by X-ray analysis and NMR spectroscopy.

机译：在碱性条件下，由[Ir（cod）Cl] _2和仲氧化膦-恶唑啉配体形成了具有P-配位次膦酸酯的芳基铱（III）氢化物配合物。这些配合物的结构涉及C-P裂解，通过X射线分析和NMR光谱确定。

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《Organometallics》 |2010年第22期|共6页
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Liniger M.; Gschwend B.; Neuburger M.; Schaffner S.; Pfaltz A.;
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1. Unprecedented reactivity of Iridium(I) secondary phosphine oxide complexes: Formation of P-coordinated phosphinate complexes by P-aryl bond cleavage [J] . Liniger M., Gschwend B., Neuburger M., Organometallics . 2010,第22期

机译：铱（I）次膦氧化物配合物的前所未有的反应性：通过P-芳基键的裂解形成P配位的次膦酸酯配合物
2. Evidence for Reversible Cyclometalation in Alkane Dehydrogenation and C-O Bond Cleavage at Iridium Bis(phosphine) Complexes [J] . Chapp Scott M., Schley Nathan D. Organometallics . 2017,第22期

机译：烷烃脱氢和铱双（膦）复合物中的烷烃脱氢和C-O键切割的证据
3. Reactivity of the triruthenium ortho-metalated cluster [Ru-3(CO)(9){mu(3)- eta(1), kappa(1),kappa(2)-PhP( C6H4) CH2PPh}] with tri(2-thienyl) phosphine and tri( 2-furyl) phosphine: Formation of 1,3-diphenyl-2,3-dihydro-1H-1,3-benzodiphosphine complexes via phosphorus-carbon bond formation [J] . Ghosh S, Rana S, Tocher DA, Journal of Organometallic Chemistry . 2009,第20期

机译：三钌正金属簇[Ru-3（CO）（9）{mu（3）-eta（1），kappa（1），kappa（2）-PhP（C6H4）CH2PPh}的反应性与tri（2 -噻吩基膦和三（2-呋喃基）膦：通过形成磷-碳键形成1,3-二苯基-2,3-二氢-1H-1,3-苯并二膦配合物
4. Metal–Ligand Cooperative C–H Bond Formation and Cleavage by Cyclopentadienone Platinum Complexes [C] . Takuya Higashi, Hideaki Ando, Shuhei Kusumoto 日本化学会春季年会講演予稿集 . 2018

机译：金属 - 配体C-H键形成和裂解依苯甲酸铂铂复合物
5. Catalytic C-C (C-N) Bond Formation and C-O Bond Cleavage by Pincer-Ligated Iridium Complexes [D] . Li, Bo. 2019

机译：掺杂剂铱络合物催化C-C（C-N）键合形成和C-O键切割
6. Crystal structures of two PCN pincer iridium complexes and one PCP pincer carbodiphosphorane iridium intermediate: substitution of one phosphine moiety of a carbodiphosphorane by an organic azide [O] . Gabriel Julian Partl, Felix Nussbaumer, Walter Schuh, 2019

机译：两种PCN夹钳铱配合物和一种PCP夹钳碳二膦铱铱的晶体结构：有机叠氮化物取代碳二膦烷的一个膦部分
7. Coordination Chemistry and Reactivity of New Zwitterionic Rhodium and Iridium Complexes Featuring the Tripodal Phosphine Ligand PhB(CH2PiPr2)3-. Activation of H-H, Si-H, and Ligand B-C Bonds [O] . -1

机译：新的两性离子铑和铱络合物的协调化学和反应性，具有三码磷酸酯磷酸酯PHB（CH2PIPR2）3-。活化H-H，Si-H和配体B-C键合
8. Preparation of B-sigma-Carboranyl Iridium Complexes by Oxidative Addition of Terminal Boron-Hydrogen Bonds to Iridium(I) Species. [R] . hoel, elvin l. hawthorne, m. f. 1975

机译：通过末端硼氢键与铱（I）物质的氧化加成制备B-sigma-Carboranyl Iridium配合物。

Unprecedented reactivity of Iridium(I) secondary phosphine oxide complexes: Formation of P-coordinated phosphinate complexes by P-aryl bond cleavage

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