Use of Aryliron Complexes [CpFe(CO)(2)Ar] as Arylcarbonyl Cation Equivalents in the Reactions with Organolithium Reagents To Yield Ketones

Yasuda S; Yorimitsu H; Oshima K

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Use of Aryliron Complexes [CpFe(CO)(2)Ar] as Arylcarbonyl Cation Equivalents in the Reactions with Organolithium Reagents To Yield Ketones

机译：芳基铁配合物[CpFe（CO）（2）Ar]在与有机锂试剂反应生成酮的反应中用作芳基羰基化阳离子当量

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Treatment of aryliron complexes [CpFe(CO)(2)Ar] with organolithium reagents RLi in THF affords the corresponding ketones RCOAr. The reaction, wherein the aryliron complexes serve as arylcarbonyl cation equivalents, would begin with nucleophilic addition of RLi to one of the carbonyl ligands to form acyliron [CpFe(CO)(RCO)Ar] without lithiation of the Cp ring.

机译：用有机锂试剂RLi在THF中处理芳基铁络合物[CpFe（CO）（2）Ar]得到相应的酮RCOAr。该反应（其中芳基铁络合物用作芳基羰基阳离子等价物）将以RLi亲核加成至羰基配体之一而开始，以形成丙烯腈[CpFe（CO）（RCO）Ar]，而无需Cp环的锂化。

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《Organometallics》 |2009年第16期|共4页
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Yasuda S; Yorimitsu H; Oshima K;
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1. Use of Aryliron Complexes [CpFe(CO)(2)Ar] as Arylcarbonyl Cation Equivalents in the Reactions with Organolithium Reagents To Yield Ketones [J] . Yasuda S, Yorimitsu H, Oshima K Organometallics . 2009,第16期

机译：芳基铁配合物[CpFe（CO）（2）Ar]在与有机锂试剂反应生成酮的反应中用作芳基羰基化阳离子当量
2. Use of Aryliron Complexes [CpFe(CO)(2)Ar] as Arylcarbonyl Cation Equivalents in the Reactions with Organolithium Reagents To Yield Ketones [J] . Yasuda S, Yorimitsu H, Oshima K Organometallics . 2009,第16期

机译：芳基铁配合物[CpFe（CO）（2）Ar]在与有机锂试剂反应生成酮的反应中用作芳基羰基化阳离子当量
3. Synthesis of Aryliron Complexes [CpFe(CO)₂Ar] by Palladium-Catalyzed Reactions of [CpFe(CO)₂I] with Arylzinc, -Boron, or -Indium Reagents [J] . Hideki Yorimitsu, Koichiro Oshima Materials . 2009,第3期

机译：钯催化[CpFe（CO）_{2 I]与芳锌，-硼或-铟试剂的钯催化合成芳铁配合物[CpFe（CO）_{2 Ar]}}
4. Synthesis of Aryliron Complexes by Palladium-Catalyzed Transmetalation between CpFe(CO)2I and Arylmetal Reagents [C] . Shigeo Yasuda, Yoshihiro Asada, Bideki Yorimitsu Symposium on Organometallic Chemistry . 2008

机译：通过CPFE（CO）2I和芳基 - 试剂之间的钯催化透射率来合成芳基络合物
5. I. The structure and reactivity of chelated organolithium reagents. II. Application of the equilibrium isotope effect to organolithium reagents. [D] . Thompson, Jennifer Leigh. 1999

机译：I.螯合有机锂试剂的结构和反应性。二。平衡同位素效应在有机锂试剂上的应用。
6. Synthesis of Aryliron Complexes CpFe(CO)2Ar by Palladium-Catalyzed Reactions of CpFe(CO)2I with Arylzinc -Boron or -Indium Reagents [O] . Shigeo Yasuda, Yoshihiro Asada, Hideki Yorimitsu, 2009

机译：钯催化的CpFe（CO）2I与芳锌-硼或-铟试剂的钯催化合成芳铁配合物CpFe（CO）2Ar
7. Synthesis of Aryliron Complexes [CpFe(CO)2Ar] by Palladium-Catalyzed Reactions of [CpFe(CO)2I] with Arylzinc, -Boron, or -Indium Reagents [O] . Koichiro Oshima, Hideki Yorimitsu, Yoshihiro Asada, 2009

机译：钯催化[CpFe（CO）2I]与芳基锌， - 硼或铟试剂反应合成aryl铁络合物[CpFe（CO）2ar]
8. New Trifluorosilyl Exchange Reagent: Reactions of Cd(SiF3)2.glyme (glyme = dimethoxyethane) with Dibromo Metal Phosphine Complexes of Platinum, Palladium, and Nickel yield Trifluorosilyl Substituted Dialkyl Compounds. [R] . Guerra, M. A., Lagow, R. J. 1990

机译：新的三氟甲硅烷基交换试剂：Cd（siF3）2甘氨酸（甘醇二甲醚=二甲氧基乙烷）与铂，钯和镍的二溴金属膦配合物的反应产生三氟甲硅烷基取代的二烷基化合物。

Use of Aryliron Complexes [CpFe(CO)(2)Ar] as Arylcarbonyl Cation Equivalents in the Reactions with Organolithium Reagents To Yield Ketones

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