Acyclic Diamino Carbene Complexes of Manganese(I): Synthesis, Deprotonation, and Subsequent Multiple Insertion Reaction of Alkynes

Ruiz J; Perandones BF

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Acyclic Diamino Carbene Complexes of Manganese(I): Synthesis, Deprotonation, and Subsequent Multiple Insertion Reaction of Alkynes

机译：锰的无环二氨基碳烯配合物（I）：炔烃的合成，去质子化和随后的多次插入反应

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The cationic isocyanide complexes fac-[Mn(CNR)(CO)(3)(bipy)](+) (1) react with NH2CH3 to give acyclic diaminocarbene (ADC) complexes fac-[Mn(ADC)(CO)(3)(bipy)](+) (2), which when treated with KOH yield neutral formamidinyl (ADC-H) derivates fac-[Mn(ADC-H)(CO)(3)(bipy)] (3). These undergo multiple insertion reactions of methyl propiolate or phenyl acetylene into the metal-carbon bond to afford compounds 4 and 5 containing a new eta(4)-azacyclohexadienyl ligand, with the loss of the bipy chelating ligand.

机译：阳离子异氰化物配合物fac- [Mn（CNR）（CO）（3）（bipy）]（+）（1）与NH2CH3反应生成无环二氨基卡宾（ADC）配合物fac- [Mn（ADC）（CO）（3））（bipy）]（+）（2），当用KOH处理时会产生中性甲酰胺基（ADC-H），衍生出fac- [Mn（ADC-H）（CO）（3）（bipy）]（3）。它们经历丙酸甲酯或苯基乙炔多次插入金属-碳键中的反应，以提供含有新的eta（4）-氮杂环己二烯基配体的化合物4和5，而失去了联吡啶螯合配体。

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《Organometallics》 |2009年第3期|共7页
作者
Ruiz J; Perandones BF;
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N-HETEROCYCLIC CARBENE; BIS(ACYCLIC DIAMINOCARBENE) COMPLEX; CROSS-COUPLING REACTIONS; METAL-COMPLEXES; ORGANOMETALLIC CHEMISTRY; MIGRATORY INSERTION; ISOCYANIDE LIGANDS; CATALYTIC-ACTIVITY; STABLE CARBENES; PALLADIUM;

机译：N-杂环碳;双（双环氨基碳）络合物;交叉偶联反应;金属络合物;有机金属化学;迁移率;异氰酸酯配体;催化活性;稳定的碳;钯;

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1. Acyclic Diamino Carbene Complexes of Manganese(I): Synthesis, Deprotonation, and Subsequent Multiple Insertion Reaction of Alkynes [J] . Ruiz J, Perandones BF Organometallics . 2009,第3期

机译：锰的无环二氨基碳烯配合物（I）：炔烃的合成，去质子化和随后的多次插入反应
2. Cascade reactions of dialkynyl Fischer carbene complexes involving intramolecular alkyne insertions oriented to the synthesis of functionalized polycycles [J] . Barluenga J, Fananas-Mastral M, Andina F, Organometallics . 2008,第14期

机译：二炔基菲舍尔卡宾配合物的级联反应，涉及分子内炔烃插入，旨在合成功能化多环
3. Reaction of Propargylsilanes with Chromium Carbene Complexes: Synthesis of Conjugated Diene Enol Ethers through a Tandem Alkyne Insertion- 1,2-Silicon Shift Process [J] . James W. Herndon, Paren P. Patel The Journal of Organic Chemistry . 1996,第14期

机译：炔丙基硅烷与铬-碳配合物的反应：通过串联炔烃插入1,2-硅转移过程合成共轭二烯烯醇醚
4. Synthesis and Alkyne-insertion Reactions of Silyl(germyl)-and Germyl(stannyl)platinum(II)Complexes [C] . Takashi Sagawa, Fumiyuki Ozawa Symposium on Organometallic Chemistry . 2003

机译：甲硅烷基（盐酸）-Andsmyl（叔尼烷基）铂（II）复合物的合成和炔烃插入反应
5. Studies of coupling reactions of Fischer carbene complexes with highly conjugated alkynes. [D] . Duan, Shaofeng. 2007

机译：费歇尔卡宾配合物与高度共轭炔烃的偶联反应研究。
6. Au(III)- versus Au(I)-induced cyclization: synthesis of 6-membered mesoionic carbene and acyclic (aryl)(heteroaryl) carbene complexes [O] . Gaël Ung, Dr. Michele Soleilhavoup, Prof. Guy Bertrand -1

机译：Au（iii） - 与Au（i）诱导的环化：合成6-元碘酸菜和无环（芳基）（杂芳基）carbene络合物
7. Base-Promoted Transmetalation Reactions of Protic NHeterocyclic Carbenes and Acyclic Diamino Carbenes from MnI to AuI: A Mechanistic Study [O] . -1

机译：来自MNI至Aui的质子中环环碳碳和共胞胺碳酸的基础促进的透明反应：机械研究
8. Chemistry of Polynuclear Metal Complexes with Bridging Carbene or Carbyne Ligands. Part 90. (1) Synthesis of the Complexes (W2M2(mu-CO)(mu-CMe)(mu3-CMe)-(Mu-PPh2)2(CO)3(eta-C5H5)2) (M = Rh or Ir) and Related Tetra- and Penta-nuclear Metal Compounds: Interconversion of Ketenyl and Lambda(5) -Phospha-alkyne Ligands Bridging Tungsten-Rhodium Bonds. [R] . Davies, S. J., Stone, F. G. 1989

机译：具有桥接卡宾或卡宾配体的多核金属配合物的化学。部分90.（1）配合物的合成（W2m2（mu-CO）（mu-Cme）（mu3-Cme） - （mu-pph2）2（CO）3（eta-C5H5）2）（m = Rh或Ir）和相关的四核和五核金属化合物：Ketenyl和Lambda（5）-phospha-alkyne配体桥联钨 - 铑键的相互转化。

Acyclic Diamino Carbene Complexes of Manganese(I): Synthesis, Deprotonation, and Subsequent Multiple Insertion Reaction of Alkynes

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