Metalated-arene-phosphino ligands: A novel approach to open-sided gold compounds

Axet M.R.; Barbazanges M.; Augè M.; Desmarets C.; Moussa J.; Ollivier C.; Aubert C.; Fensterbank L.; Gandon V.; Malacria M.; Chamoreau L.M.; Amouri H.

首页> 外文期刊>Organometallics >Metalated-arene-phosphino ligands: A novel approach to open-sided gold compounds

【24h】

Metalated-arene-phosphino ligands: A novel approach to open-sided gold compounds

机译：金属化的芳烃膦配体：一种新型的敞开式金化合物

获取原文

获取原文并翻译 | 示例

掌桥外文数据库（机构版） >>

开具论文收录证明 >>

文献代查 >>

页面导航

摘要
著录项
相似文献
相关主题

摘要

A novel type of metalated phosphino ligands, [Cp*Ru (η~6-arene-PPh_2)][OTf] (2a-d-OTf), has been prepared in which the -PPh2 unit is attached to a metalated π-arene platform. This unique class of ligands 2a-d are converted to open-sided cationic gold complexes 3a-d upon treatment with [AuCl(tht)]. The structure of one of these compounds, [Cp*Ru(η~6-C _6H_5-PPh_2-Au-Cl)][OTf] (3a-OTf), was ascertained by single-crystal X-ray diffraction. Preliminary studies suggest that cationic complex 3a is active in metal-catalyzed cycloisomerization reactions.

机译：已经制备了新型的金属化膦配体[Cp * Ru（η〜6-芳烃-PPh_2）] [OTf]（2a-d-OTf），其中-PPh2单元连接到金属化的π-芳烃上平台。在用[AuCl（tht）]处理后，这种独特的配体类别2a-d被转化为敞开侧的阳离子金络合物3a-d。通过单晶X射线衍射确定其中一种化合物[Cp * Ru（η〜6-C _6H_5-PPh_2-Au-Cl）] [OTf]（3a-OTf）的结构。初步研究表明，阳离子络合物3a在金属催化的环异构化反应中具有活性。

著录项

来源
《Organometallics》 |2010年第24期|共3页
作者
Axet M.R.; Barbazanges M.; Augè M.; Desmarets C.; Moussa J.; Ollivier C.; Aubert C.; Fensterbank L.; Gandon V.; Malacria M.; Chamoreau L.M.; Amouri H.;
展开▼
作者单位

展开▼
收录信息
原文格式 PDF
正文语种 eng
中图分类
关键词

相似文献

外文文献
中文文献
专利

1. Metalated-arene-phosphino ligands: A novel approach to open-sided gold compounds [J] . Axet M.R., Barbazanges M., Augè M., Organometallics . 2010,第24期

机译：金属化的芳烃膦配体：一种新型的敞开式金化合物
2. Anticancer Gold(III) Compounds With Porphyrin or N-heterocyclic Carbene Ligands [J] . Tong Ka-Chung, Hu Di, Wan Pui-Ki, Frontiers in Chemistry . 2020,第3期

机译：抗癌金（III）卟啉或N-杂环配体的化合物
3. Controlling the Thermal Stability and Volatility of Organogold(I) Compounds for Vapor Deposition with Complementary Ligand Design [J] . Griffiths Matthew B. E., Dubrawski Zachary S., Bacic Goran, European journal of inorganic chemistry . 2019,第46期

机译：用互补配体设计控制用于气相沉积的有机轧制（I）化合物的热稳定性和挥发性
4. A Simple and Efficient Approach to Prepare One-Bead One-Compound Cyclic Peptide Libraries for Ligands Identification [C] . Anick Girard, Francois Bedard, Eric Biron American Peptide Symposium . 2011

机译：一种简单有效的方法，用于制备单珠单体复合环状肽文库的配体鉴定
5. A non-derivatization approach to HPLC fluorescence detection for some important amino group-containing compounds based on a ligand displacement reaction. [D] . Yang, Min. 2000

机译：基于配体置换反应的一些重要的含氨基化合物的HPLC荧光检测的非衍生化方法。
6. Synchrotron Characterization of Hexagonal and Cubic Lipidic Phases Loaded with Azolate/Phosphane Gold(I) Compounds: A New Approach to the Uploading of Gold(I)-Based Drugs [O] . Paola Astolfi, Michela Pisani, Elisabetta Giorgini, 2020

机译：加载含唑酯/磷酸金（I）化合物的六边形和立方脂质相的同步表征：新的金（I）的新方法 - 基于药物
7. Gold Complexes with Tridentate Cyclometalating and NHC Ligands: A Search for New Photoluminescent Gold(III) Compounds [O] . Herbst, Annika, Bronner, Catherine, Dechambenoit, Pierre, 2013

机译：具有三齿环金属化和NHC配体的金配合物：寻找新的光致发光金（III）化合物
8. Moessbauer Studies of Non-Linear Excitations and Gold Cluster Compounds. An Experimental Investigation of Non-Linear Excitations in Ising-Like Antiferromagnetic Chain Systems and of Metal Core Atoms in Polynuclear Gold Cluster Compounds. [R] . Smit, H. H. A. 1988

机译：moessbauer研究非线性激发和金簇化合物。多核金簇化合物中Ising样反铁磁链系统和金属核原子非线性激发的实验研究。

Metalated-arene-phosphino ligands: A novel approach to open-sided gold compounds

摘要

著录项

相似文献

相关主题

期刊订阅