Stoichiometric and catalytic cross dimerization between butadiene and methyl acrylate promoted by a Ruthenium(0) complex

Hirano M.; Arai Y.; Komine N.; Komiya S.

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Stoichiometric and catalytic cross dimerization between butadiene and methyl acrylate promoted by a Ruthenium(0) complex

机译：钌（0）配合物促进丁二烯与丙烯酸甲酯之间的化学计量和催化交叉二聚

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Treatment of Ru(η~4-butadiene)(η~4-1,5-COD) (NCMe) (1a) with methyl acrylate in benzene for 3 h at 6 °C produces Ru{cisoid-η~4-(2E,4E)-(methyl hepta-2,4-dienoate)} (η~4-1,5-COD)(NCMe) (2a) in 97% yield. Complex 1a (2 mol %) catalyzes the chemoselective cross dimerization between butadiene and methyl acrylate in benzene to give a mixture of the regioisomers of methyl heptadienoate in 43% yield by the oxidative coupling reaction.

机译：在6°C下用丙烯酸甲酯在苯中处理Ru（η〜4-丁二烯）（η〜4-1,5-COD）（NCMe）（1a）3小时，生成Ru {cisoid-η〜4-（2E），4E）-（甲基七-2,4-二烯酸甲酯）}（η〜4-1,5-COD）（NCMe）（2a），产率为97％。络合物1a（2mol％）催化苯中丁二烯和丙烯酸甲酯之间的化学选择性交叉二聚，通过氧化偶联反应以43％的产率得到庚二烯酸甲酯的区域异构体的混合物。

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《Organometallics》 |2010年第22期|共3页
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Hirano M.; Arai Y.; Komine N.; Komiya S.;
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1. Stoichiometric and catalytic cross dimerization between butadiene and methyl acrylate promoted by a Ruthenium(0) complex [J] . Hirano M., Arai Y., Komine N., Organometallics . 2010,第22期

机译：钌（0）配合物促进丁二烯与丙烯酸甲酯之间的化学计量和催化交叉二聚
2. Catalytic tail-to-tail selective dimerization of methyl methacrylate promoted by a ruthenium(0) complex [J] . Hirano M., Hiroi Y., Komine N., Organometallics . 2010,第17期

机译：钌（0）配合物催化的甲基丙烯酸甲酯的尾到尾选择性二聚反应
3. Isolation of trans-2,5-Bis(methoxycarbonyl)ruthenacyclopentane by Oxidative Coupling of Methyl Acrylate on Ruthenium(0) as an Active Intermediate for Tail-to-Tail Selective Catalytic Dimerization [J] . Hirano M, Sakate Y, Komine N, Organometallics . 2009,第17期

机译：甲基丙烯酸甲酯在钌（0）上的氧化偶联作为反式2,5-双（甲氧基羰基）钌环戊烷的活性中间体，用于尾对尾选择性催化二聚
4. CATALYTIC DIMERIZATION OF METHYL ACRYLATE UNDER SUPERCRITICAL CARBON DIOXIDE-IONIC LIQUID BIPHASIC MEDIUM [C] . D. Ballivet-Tkatchenko, M. Picquet, M. Solinas, International Symposium on Supercritical Fluids Tome 2: SCF Properties Reactions; 20030428-20030430; Versailles; FR . 2003

机译：超临界二氧化碳-离子液体双相介质下丙烯酸甲酯的催化二聚
5. I. Stereochemistry of cyclopropane formation involving group (IV) organometallic complexes. II. Slower stoichiometric and faster catalytic reduction of aldehydes by the PPh(3) substituted hydroxycyclopentadienyl ruthenium hydride [2,5-Ph(2)-3,4-Tol(2)(eta(5)-C(4)COH)]Ru(CO)(PPh(3))H: A highly chemoselective catalyst for hydrogenation of aldehydes over ketones. [D] . Strotman, Neil Adham. 2005

机译：I.涉及（IV）族有机金属配合物的环丙烷形成的立体化学。二。由PPh（3）取代的羟基环戊二烯基氢化钌[2,5-Ph（2）-3,4-Tol（2）（eta（5）-C（4）COH）] Ru的化学计量较慢和较快的醛催化还原（CO）（PPh（3））H：一种高度化学选择性的催化剂，用于醛在酮上的氢化。
6. Geometry Constrained N-(567-Trihydroquinolin-8-ylidene)arylaminopalladium Dichloride Complexes: Catalytic Behavior toward Methyl Acrylate (MA) Methyl Acrylate-co-Norbornene (MA-co-NB) Polymerization and Heck Coupling [O] . Yanning Zeng, Qaiser Mahmood, Tongling Liang, 2016

机译：几何约束的N-（567-三氢喹啉-8-亚烷基）芳基氨基钯二氯化物配合物：对丙烯酸甲酯（MA）丙烯酸甲酯-共降冰片烯（MA-co-NB）聚合和Heck偶联的催化行为
7. Mechanistic insights into catalytic linear cross-dimerization between conjugated dienes and styrenes by a ruthenium(0) complex [O] . Masafumi Hirano, Takao Ueda, Nobuyuki Komine, 2015

机译：通过钌（0）复合物在共轭二烯和苯乙烯之间的催化线性交叉二聚化的机械洞察力
8. Electropolymerization of Ruthenium Bis(1,10-phenanthroline)(4-methyl-4'vinyl-2,2'-bipyridine) Complexes through Direct Attack on the Ligand Ring System [R] . Guarr, T. F., Anson, F. C. 1987

机译：直接攻击配体环系统对双（1,10-菲咯啉）（4-甲基-4'-乙烯基-2,2'-联吡啶）配合物的电聚合

Stoichiometric and catalytic cross dimerization between butadiene and methyl acrylate promoted by a Ruthenium(0) complex

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