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Facile self-assembly of dendritic multiferrocenyl hexagons and their electrochemistry

机译:树枝状多二茂铁基六角形分子的自组装及其电化学

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摘要

The design and synthesis of a new class of dendritic multiferrocenyl hexagons have been achieved via [3+3] coordination-driven self-assembly. The relative distribution of dendritic and ferrocenyl subunits on the periphery of supramolecular metallocycles can be precisely controlled. The structures of all compounds are confirmed by multinuclear NMR, ESI-MS/ESI-TOF-MS, and elemental analysis. The electrochemical properties of the newly designed dendritic multiferrocenyl complexes have been studied through cyclic voltammetry investigation.
机译:通过[3 + 3]配位驱动的自组装,实现了新型树状多二茂铁基六边形的设计和合成。可以精确控制超分子金属环外围的树枝状和二茂铁基亚基的相对分布。所有化合物的结构均通过多核NMR,ESI-MS / ESI-TOF-MS和元素分析确定。通过循环伏安法研究了新设计的树枝状多二茂铁基配合物的电化学性质。

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