Transmetalation of alkyl ligands from Cp~*(PMe_3)IrR~1~R~2 to (cod)PtR~3X

Durak L.J.; Lewis J.C.

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Transmetalation of alkyl ligands from Cp~*(PMe_3)IrR~1~R~2 to (cod)PtR~3X

机译：烷基配体从Cp〜*（PMe_3）IrR〜1〜R〜2到（cod）PtR〜3X的金属转移

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Transmetalation of alkyl and carboxylate ligands between Cp~*(PMe_3)Ir complexes and d~8 Pt and Pd complexes is described. Studies on the scope and kinetics of this reaction support a mechanism in which carboxylate dissociation from the Pt or Pd center precedes alkyl transfer from Ir. Subsequent reaction of the resulting Pt or Pd alkyl complex enables functionalization of the hydrocarbyl ligands and suggests new opportunities for catalytic, nondirected C-C and C-H bond functionalization reactions.

机译：描述了Cp〜*（PMe_3）Ir配合物与d〜8 Pt和Pd配合物之间烷基和羧酸盐配体的金属转移。关于该反应的范围和动力学的研究支持了一种机制，其中从Pt或Pd中心解离的羧酸盐先于从Ir的烷基转移。所得的Pt或Pd烷基络合物的随后反应使得能够使烃基配体官能化，并为催化的，非定向的C-C和C-H键官能化反应提出了新的机会。

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来源
《Organometallics》 |2013年第11期|共4页
作者
Durak L.J.; Lewis J.C.;
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正文语种 eng
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关键词
alkyl; carboxylate; complexes;

机译：烷基;羧酸盐;络合物;

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1. Transmetalation of alkyl ligands from Cp~*(PMe_3)IrR~1~R~2 to (cod)PtR~3X [J] . Durak L.J., Lewis J.C. Organometallics . 2013,第11期

机译：烷基配体从Cp〜*（PMe_3）IrR〜1〜R〜2到（cod）PtR〜3X的金属转移
2. Ruthenium(II) chemistry of phosphorus-based ligands, Ph2PN(R)PPh2 (R = Me or Ph) and Ph2PN(Ph)P(E) Ph-2 (E = S or Se). Solution thermochemical study of ligand substitution reactions in the Cp ' RuCl(COD) (Cp ' = Cp, Cp*; COD = cyclooctadiene) system [J] . Balakrishna MS., Smith DC., Klaman A., Journal of Organometallic Chemistry . 2000,第2期

机译：磷基配体Ph2PN（R）PPh2（R = Me或Ph）和Ph2PN（Ph）P（E）Ph-2（E = S或Se）的钌（II）化学。 Cp'RuCl（COD）（Cp'= Cp，Cp *; COD =环辛二烯）系统中配体取代反应的溶液热化学研究
3. Intermolecular Activation of Hydrocarbon C-H Bonds Initiated by the Tungsten Hydrocarbyl Hydrido Complexes Cp*W(NO)(R)(H)(PMe_3) (R = Alkyl,Aryl) [J] . Kajin Lee, Peter Legzdins, Craig B.Pamplin, Organometallics . 2005,第4期

机译：钨烃基氢配合物Cp * W（NO）（R）（H）（PMe_3）（R =烷基，芳基）引发的烃C-H键的分子间活化
4. Single-Electron Transmetalation: Radical Mediated Alkyl Transfer in Cross-Coupling - (PPT) [C] . David N. Primer International Precious Metals Institute Annual Conference . 2017

机译：单电子传递：基于偶联中的自由基介导的烷基转移 - （PPT）
5. The Chemistry of Metal Complexes Derived from Heteroatom-Stabilized Alkyl Ligands and a Pyridyl-1-Azaallyl Ligand [D] . Choi, Tsz Hei. 2019

机译：金属配合物的化学源自杂原子稳定的烷基配体和吡啶基-1-α111allyL配体
6. Pendant Ancillary Ligand Switches Off Auto-Oxidation of Group 13 Metal Alkyl Compounds Bearing Non-Bulky Alkyl Groups [O] . Issam Kobrsi -1

机译：悬垂辅助配体关闭具有非大烷基的13族金属烷基化合物的自氧化
7. Chemical Properties of Mononuclear and Dinuclear Phenylplatinum(II) Hydroxo Complexes with Cod Ligands. Transmetalation of Arylboronic Acids, Coupling of the Phenyl Ligands, and Carbonylation [O] . -1

机译：单核和二核苯乙烯（II）与COD配体的羟基络合物的化学性质。芳基硼酸的透射率，苯基配体的偶联和羰基化

Transmetalation of alkyl ligands from Cp~*(PMe_3)IrR~1~R~2 to (cod)PtR~3X

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