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首页> 外文期刊>Synthetic Metals >Electrochemical polymerization and in situ FTIRS study of conducting polymers obtained from o-aminobenzoic with aniline at platinum electrodes
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Electrochemical polymerization and in situ FTIRS study of conducting polymers obtained from o-aminobenzoic with aniline at platinum electrodes

机译:邻氨基苯甲酸与苯胺在铂电极上得到的导电聚合物的电化学聚合和原位FTIRS研究

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摘要

The electrochemical copolymerization of o-aminobenzoic acid with aniline (ANI) was carried out on platinum electrodes in perchloric acid aqueous medium by cyclic scanning of the potential.Electrochemical homopolymerization of o-aminobenzoic acid was also done. Experimental results showed that the polymers are formed in all cases and the presence of aniline promoted markedly the growth of the rate of copolymerization. The obtained polymer films have been characterized by cyclic voltammetry and in situ Fourier transform infrared (FTIR) spectroscopy. The mechanism of the electrochemical polymerization reaction has been discussed.
机译:通过循环扫描电势在高氯酸水介质中在铂电极上进行邻氨基苯甲酸与苯胺(ANI)的电化学共聚合,并进行邻氨基苯甲酸的电化学均聚。实验结果表明,在所有情况下均会形成聚合物,并且苯胺的存在显着促进了共聚速率的增长。所获得的聚合物膜已经通过循环伏安法和原位傅立叶变换红外光谱(FTIR)进行了表征。已经讨论了电化学聚合反应的机理。

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