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Conducting fabrics of polyester coated with polypyrrole and doped with graphene oxide

机译:涂覆有聚吡咯和氧化石墨烯的聚酯导电织物

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Polyester (PES) has been coated with polypyrrole (PPy) to produce conducting fabrics. Graphene oxide (GO) has been used in different concentrations (10, 20 and 30% weight) as counter ion to neutralize the positive charges of the PPy structure. Fourier transform infrared spectroscopy with attenuated total reflection (FTIR-ATR), energy dispersive X-ray (EDX) and X-ray photoelectron spectroscopy (XPS) of the PPy/GO powders corroborated the incorporation of GO as counter ion due to the presence of 0 in the EDX spectrum, as well as an excess of C, arising from GO contribution. The doping level (N+/N) decreased with the GO content. Field emission scanning electron microscopy (FESEM) showed the formation of the PPy/GO coating and the incorporation of GO in the composite. Electrochemical impedance spectroscopy (EIS) in solid state and solution, cyclic voltammetry (CV) and scanning electrochemical microscopy (SECM) were used to test the electrical properties and electroactivity of the fabrics. There was a decrease in the electrical properties and electroactivity as the GO content increased. The conductivity of the fabrics could be tuned by varying the GO content. (C) 2015 Elsevier B.V. All rights reserved.
机译:聚酯(PES)涂有聚吡咯(PPy)以生产导电织物。氧化石墨烯(GO)已以不同浓度(10%,20%和30%重量)用作抗衡离子,以中和PPy结构的正电荷。 PPy / GO粉末的傅里叶变换红外光谱与衰减全反射(FTIR-ATR),能量色散X射线(EDX)和X射线光电子能谱(XPS)证实了GO作为反离子的掺入由于GO贡献,EDX光谱中的0以及过量的C。掺杂水平(N + / N)随GO含量的增加而降低。场发射扫描电子显微镜(FESEM)显示了PPy / GO涂层的形成以及GO在复合材料中的结合。固态和溶液中的电化学阻抗谱(EIS),循环伏安法(CV)和扫描电化学显微镜(SECM)用于测试织物的电性能和电活性。随着GO含量的增加,电性能和电活性降低。可以通过改变GO含量来调节织物的电导率。 (C)2015 Elsevier B.V.保留所有权利。

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