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Dielectric properties of the ternary TeO2/Nb2O5/ZnO glasses

机译:TeO2 / Nb2O5 / ZnO三元玻璃的介电性能

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Glasses of the system TeO2/Nb2O5/ZnO containing different concentration of ZnO (ranging from 5 to 20 mol%) were prepared. The dielectric properties over wide ranges of frequencies and temperatures were investigated as a function of ZnO content by impedance spectroscopy measurements. The impedance spectra of the present glasses were modeled by appropriate equivalent circuit. The dielectric constant has a value of 66 for the 85TeO(2)/10Nb(2)O(5)/5ZnO glass which is three times larger than that of pure TeO2 glass and other binary, e.g. TeO2/ZnCl2, tellurite glassy systems. The results have been analyzed in light of varying NbO6 octahedra and NbO4 tetrahedra of niobium oxide as zinc oxide varies from 5 to 20 mol%. The relaxation properties of the investigated glasses are presented in the electric modulus formalism, where the relaxation time and the respective activation energy are determined. (c) 2005 Elsevier B.V. All rights reserved.
机译:制备含有不同浓度的ZnO(5至20mol%)的TeO 2 / Nb 2 O 5 / ZnO体系的玻璃。通过阻抗谱测量,研究了在很宽的频率和温度范围内的介电特性,它们是ZnO含量的函数。本眼镜的阻抗谱通过适当的等效电路建模。 85TeO(2)/ 10Nb(2)O(5)/ 5ZnO玻璃的介电常数值为66,比纯TeO2玻璃和其他二元玻璃(例如,0.5N)的介电常数大三倍。 TeO2 / ZnCl2,亚碲酸盐玻璃状体系。根据氧化铌的NbO6八面体和NbO4四面体的NbO4四面体的变化对结果进行了分析,因为氧化锌的摩尔百分比为5至20 mol%。所研究的玻璃的弛豫特性以电子模量形式表示,其中确定了弛豫时间和相应的活化能。 (c)2005 Elsevier B.V.保留所有权利。

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