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Hyperfine spectroscopy and characterization of muonium in ZnGeP_2

机译:ZnGeP_2中mu的超精细光谱学和表征

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In this contribution, we report the initial observation of neutral muonium defect centers in ZnGeP2. The spin-precession frequencies in a 4.0 T field yield a zero-temperature hyperfine constant of ~1965MHz for the promptly formed Mu~0 state. Subsequently, we performed T~(-1) _1 longitudinal depolarization measurements in low magnetic fields. Decoupling curves show a different anisotropic Mu0 with A_2=3185MHz and D=374MHz, where D is the dipolar contribution. The relaxation rates suggest rapid diffusion of Mu~0, most likely via quantum tunneling below 80 K and by thermally activated hops above 100 K. We have determined the ionization energy to be roughly 200meV. We present our preliminary evaluation of the motion or site transition dynamics in addition to hyperfine characterization of the neutral muonium centers observed in ZnGeP2.
机译:在此贡献中,我们报告了ZnGeP2中性mu缺陷中心的初步观察。对于迅速形成的Mu〜0态,在4.0 T场中的自旋进动频率产生了〜1965MHz的零温度超精细常数。随后,我们在低磁场中进行了T〜(-1)_1纵向去极化测量。解耦曲线显示了一个不同的各向异性Mu0,A_2 = 3185MHz,D = 374MHz,其中D是偶极贡献。弛豫速率表明Mu〜0的快速扩散,很可能是通过80 K以下的量子隧穿和100 K以上的热活化跃变引起的。我们确定电离能约为200meV。我们目前对运动或站点过渡动力学的初步评估,以及在ZnGeP2中观察到的中性mu中心的超精细特征。

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