Molecular material-{N(n-C4H9)(4)[Ni(II)(0.5) Fe(II)(0.5) Fe(III)(C2O4)(3)]}(infinity): Magnetic, Mossbauer and electrical conductivity studies

Bhattacharjee A; Bhakat D

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Molecular material-{N(n-C4H9)(4)[Ni(II)(0.5) Fe(II)(0.5) Fe(III)(C2O4)(3)]}(infinity): Magnetic, Mossbauer and electrical conductivity studies

机译：分子材料-{N（n-C4H9）（4）[Ni（II）（0.5）Fe（II）（0.5）Fe（III）（C2O4）（3）]}（无穷大）：磁，莫斯鲍尔和电导率学习

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We have attempted to characterize the magnetic and electrical properties of a new mixed-metal molecular material {NBu4[Ni(II)(0.5)Fe(II)(0.5)Fe(III)(ox)(3)]}(N) synthesized by the use of trioxalatoferrate as the building block. Mossbauer spectroscopy was utilized in order to understand local spin structures in this compound. The results indicate that the compound is a semiconducting ferrimagnet with T-N = 30 K and room temperature conductivity of 6 x 10(-15) Omega(-1) cm(-1) along with 1.8 eV activation energy under dark. The compound has no appreciable electrical response towards illumination.

机译：我们试图表征一种新型混合金属分子材料{NBu4 [Ni（II）（0.5）Fe（II）（0.5）Fe（III）（ox）（3）]}（N）的磁性能和电性能通过使用三氧杂草酸高铁酸盐作为结构单元合成。为了了解该化合物中的局部自旋结构，使用了莫斯鲍尔光谱。结果表明，该化合物为半导电铁氧体，T-N = 30 K，室温电导率为6 x 10（-15）Omega（-1）cm（-1），在黑暗中的活化能为1.8 eV。该化合物对照明没有明显的电响应。

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《Physica, B. Condensed Matter》 |2009年第20期|共4页
作者
Bhattacharjee A; Bhakat D;
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正文语种 eng
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Molecular material; Oxalate; Ferrimagnet; Mossbauer study; Semiconductor;

机译：分子材料;草酸盐;铁磁体;Mossbauer研究;半导体;

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1. Molecular material-{N(n-C4H9)(4)[Ni(II)(0.5) Fe(II)(0.5) Fe(III)(C2O4)(3)]}(infinity): Magnetic, Mossbauer and electrical conductivity studies [J] . Bhattacharjee A, Bhakat D Physica, B. Condensed Matter . 2009,第20期

机译：分子材料-{N（n-C4H9）（4）[Ni（II）（0.5）Fe（II）（0.5）Fe（III）（C2O4）（3）]}（无穷大）：磁，莫斯鲍尔和电导率学习
2. Mossbauer spectroscopy under a magnetic field to explore the low-temperature spin structure of the layered ferrimagnetic material - {N(n-C4H9)(4)[(FeFeIII)-Fe-II(C2O4)(3)]}(infinity) [J] . Bhattacharjee A., Reiman S., Ksenofontov V., Journal of Physics. Condensed Matter . 2003,第29期

机译：磁场下的莫斯鲍尔光谱研究层状亚铁磁性材料的低温自旋结构-{N（n-C4H9）（4）[（FeFeIII）-Fe-II（C2O4）（3）]}（无穷大）
3. Muon spin relaxation studies of magnetic ordering in the molecular-based ferrimagnets (PPh4MnFeIII)-Fe-II(C2O4)(3) and (n-C4H9)(4)(NFeFeIII)-Fe-II(C2O4)(3) [J] . Watts ID., Day P., Visser D., Journal of Physics. Condensed Matter . 2001,第10期

机译：分子基铁氧体（PPh4MnFeIII）-Fe-II（C2O4）（3）和（n-C4H9）（4）（NFeFeIII）-Fe-II（C2O4）（3）中磁有序的Muon自旋弛豫研究
4. Biocompatibiiity study of Mn_(0.5)Zn_(0.5)Fe_2O_4 magnetic nanoparticles [C] . Jing Liu, Jia Zhang, Li Wang Annual Conference of the Chinese Society of Micro-Nano Technology . 2011

机译：Mn_（0.5）Zn_（0.5）Fe_2O_4磁性纳米粒子的生物相容性研究
5. A Study on the Effect of Fe-Ni Variation on the Magnetocaloric Properties of Mn0.5Fe0.5+xNi1-xSi0.94Al0.06 and Mn0.5Fe0.5-xNi1+xSi0.94Al0.06 Systems [D] . Akintunde, Babajide Olaolu. 2021

机译：Fe-Ni变异对Mn0.5Fe0.5 + XNI1-XSI0.94AL0.0.06和MN0.5FE0.5-XNI1 + XSI0.94AL0.06系统磁热性性能影响的研究
6. Crystal structure of K0.75FeII3.75FeIII1.25(HPO3)6·0.5H2O an open-framework iron phosphite with mixed-valent FeII/FeIII ions [O] . Edurne S. Larrea, José Luis Mesa, Estibaliz Legarra, 2016

机译：K0.75 FeII的晶体结构3.75FeIII1.25（HPO3）6·0.5H2O具有混合的FeII / FeIII离子的开放式亚磷酸铁
7. Multiple Magnetic Pole Reversals and Mössbauer Studies in Molecular-based Mixed Valency Ferrimagnet {N(n-C4H9)4MIIFeIII(C2O4)3}n (M=Zn, Fe) [O] . Lin Qing, Lei Chenglong, Tang Guodong, 2012

机译：基于分子的混合价铁氧体{N（n-C4H9）4 MIIFeIII（C2O4）3} n（M = Zn，Fe）的多重磁极反转和Mössbauer研究

Molecular material-{N(n-C4H9)(4)[Ni(II)(0.5) Fe(II)(0.5) Fe(III)(C2O4)(3)]}(infinity): Magnetic, Mossbauer and electrical conductivity studies

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