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Temperature variation of the fundamental absorption edge in AgGaSe_2

机译:AgGaSe_2中基本吸收边的温度变化

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摘要

Optical absorption measurements were made in the temperature range 9-300 K on the chalcopyritesemiconductor compound AgGaSe2 and the optical energy gap EG determined as a function oftemperature T. In order to obtain the values of EG as a function of T, the Elliot-Toyozawa model [R.J. Elliot,J. Phys. Rev. 108 (1957) 1384; D.D. Sell, P. Lawaets, Phys. Rev. Lett. 26 (1971) 311] was employed toperform the analysis of the optical absorption spectra. The resulting EG vs. T curve was fitted to a semi-empirical model that takes into account both the thermal expansion and the electron-phononinteraction contributions. The results have been used to estimate values of the deformation potentials ofthe valence and conduction bands of the compound.
机译:在黄铜矿半导体化合物AgGaSe2上在9-300 K的温度范围内进行了光吸收测量,并确定了光能隙EG与温度T的关系。为了获得EG与T的关系,Elliot-Toyozawa模型[RJ艾略特,J。物理Rev.108(1957)1384; D.D.出售,体育律师,物理。牧师26(1971)311]被用来进行光吸收光谱的分析。所得的EG与T曲线拟合为半经验模型,该模型考虑了热膨胀和电子-声子相互作用的影响。该结果已用于估计化合物的价态和导带的变形势的值。

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