首页> 外文期刊>Physica, B. Condensed Matter >The concentration effect of upconversion luminescence properties in Er ~(3+)/Yb~(3+)-codoped Y_2(MoO_4)_3 phosphors
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The concentration effect of upconversion luminescence properties in Er ~(3+)/Yb~(3+)-codoped Y_2(MoO_4)_3 phosphors

机译:Er〜(3 +)/ Yb〜(3+)掺杂的Y_2(MoO_4)_3荧光粉的上转换发光特性的集中效应

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摘要

Y_2(MoO_4)_3:Er~3/Yb~3 phosphors with fixed (varied) Er~3 and varied (fixed) Yb~3 concentrations were synthesized by a conventional solid-state reaction. The crystal structure of the phosphors was characterized by means of X-ray diffraction (XRD). Upon 980 nm excitation, very weak blue emission, and strong green and red upconversion emissions centered at 485, 525, 545 and 656 nm were observed. The two-photon process was confirmed to be responsible for both the green and red upconversion emissions. The effects of green upconversion emission intensity ratio (~2H_(11/2)→~4I_(15/2) versus ~4S_(3/2)→~4I_(15/2)) and the integrated upconversion emission intensity on the Yb~3 and Er ~3 concentrations were studied.
机译:通过常规的固相反应合成了具有固定的(可变的)Er〜3和变化的(固定的)Yb〜3浓度的Y_2(MoO_4)_3:Er〜3 / Yb〜3荧光粉。磷光体的晶体结构通过X射线衍射(XRD)表征。在980 nm激发后,观察到非常弱的蓝色发射,以及以485、525、545和656 nm为中心的强绿色和红色上转换发射。证实了双光子过程是绿色和红色上转换发射的原因。绿色上转换发射强度比(〜2H_(11/2)→〜4I_(15/2)与〜4S_(3/2)→〜4I_(15/2))和积分上转换发射强度对Yb的影响研究了〜3和Er〜3的浓度。

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