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UV exposure and photon degradation of Alq _3 powders (Conference Paper)

机译:Alq _3粉末的紫外线暴露和光子降解(会议论文)

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摘要

Tris-(8-hydroxyquinoline)aluminum (Alq _3) is a widely used light emitting material. It is also used as an electron transporting layer in organic light emitting devices (OLEDs). Degradation is, however, a major problem in these devices. The device performance is affected by parameters such as air, moisture and light exposure [1,2]. In this work the effect of photon degradation of Alq _3 in air is investigated. Alq _3 phosphor powder was synthesized using a co-precipitation method and recrystalized in acetone. The structure of the sample was determined by using x-ray diffraction (XRD). The averaging particle size estimated from the broadened XRD peaks using Scherrers equation was 40±4 nm in diameter. The excitation photoluminescence data that was collected correspond well to the absorption data. To study the photon degradation, the sample was irradiated with an UV lamp for ~330h. The emission data was collected and the change in photoluminescence intensity with time was monitored.
机译:三(8-羟基喹啉)铝(Alq _3)是广泛使用的发光材料。它也用作有机发光器件(OLED)中的电子传输层。然而,降解是这些设备中的主要问题。器件的性能受空气,湿气和光照等参数的影响[1,2]。在这项工作中,研究了空气中Alq _3的光子降解的影响。使用共沉淀法合成Alq_3荧光粉,并在丙酮中重结晶。通过使用X射线衍射(XRD)确定样品的结构。使用Scherrers方程从扩展的XRD峰估算的平均粒径为40±4 nm。收集的激发光致发光数据与吸收数据很好地对应。为了研究光子的降解,用紫外灯照射样品约330h。收集发射数据,并监测光致发光强度随时间的变化。

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