Pendant group orientation of poly(2-vinylnaphthalene) thin film surface studied by near-edge x-ray absorption fine structure spectroscopy (NEXAFS) and angle-resolved ultraviolet photoelectron spectroscopy (ARUPS)

Morikawa E.; Okudaira KK.; Azuma Y.; Meguro K.; Harada Y.; Seki K.; Hasegawa S.; Ueno N.; Saile V.

首页> 外文期刊>The Journal of Chemical Physics >Pendant group orientation of poly(2-vinylnaphthalene) thin film surface studied by near-edge x-ray absorption fine structure spectroscopy (NEXAFS) and angle-resolved ultraviolet photoelectron spectroscopy (ARUPS)

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Pendant group orientation of poly(2-vinylnaphthalene) thin film surface studied by near-edge x-ray absorption fine structure spectroscopy (NEXAFS) and angle-resolved ultraviolet photoelectron spectroscopy (ARUPS)

机译：聚（2-乙烯基萘）薄膜表面的侧基取向通过近边缘x射线吸收精细结构光谱（NEXAFS）和角分辨紫外光电子能谱（ARUPS）研究

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Angle-resolved ultraviolet photoelectron spectroscopy (ARUPS) and near-edge x-ray absorption fine structure (NEXAFS) spectroscopy were applied to the investigation of the tilt angles of the naphthalene pendant groups at the surface of a poly(2-vinylnaphthalene) thin film. In contrast to NEXAFS, which provides only an average determination of the tilt angle, ARUPS combined with a sophisticated analysis of photoelectron angular dependence offers more detailed information. It was concluded that the naphthalene pendant groups are tilted randomly at the polymer surface, and that the tilt angle distribution is well described as a three-dimensional isotropic random orientation. (C) 2000 American Institute of Physics. [S0021-9606(00)70723-9]. [References: 27]

机译：将角分辨紫外光电子能谱（ARUPS）和近边缘X射线吸收精细结构（NEXAFS）光谱用于研究聚（2-乙烯基萘）薄膜表面萘侧基的倾斜角。与仅提供倾斜角的平均确定值的NEXAFS相比，ARUPS结合对光电子角度依赖性的复杂分析可提供更详细的信息。可以得出结论，萘侧基在聚合物表面无规倾斜，并且倾斜角分布很好地描述为三维各向同性无规取向。（C）2000美国物理研究所。 [S0021-9606（00）70723-9]。 [参考：27]

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《The Journal of Chemical Physics》 |2000年第23期|共6页
作者
Morikawa E.; Okudaira KK.; Azuma Y.; Meguro K.; Harada Y.; Seki K.; Hasegawa S.; Ueno N.; Saile V.;
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Plane-grating monochromator; Molecular-orientation; Ultrathin films; Metal-surfaces; Photoemission; Mos2; Photoionization; Radiation; Ups; H-2-phthalocyanine;

机译：平面光栅单色仪;分子取向;超薄膜;金属表面;光发射;Mos2;光电离;辐射;Ups;H-2-酞菁;

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机译：聚（2-乙烯基萘）薄膜表面的侧基取向通过近边缘x射线吸收精细结构光谱（NEXAFS）和角分辨紫外光电子能谱（ARUPS）研究
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Pendant group orientation of poly(2-vinylnaphthalene) thin film surface studied by near-edge x-ray absorption fine structure spectroscopy (NEXAFS) and angle-resolved ultraviolet photoelectron spectroscopy (ARUPS)

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