H and CH_3 eliminations in the photodissociation of chlorotoluene

Ming-Fu Lin; Cheng-Liang huang; Vadim V.Kislov; A.M.Mebel; Yuan T.Lee; Chi-Kung Ni

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H and CH_3 eliminations in the photodissociation of chlorotoluene

机译：氯甲苯光解中的H和CH_3消除

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Photodissociation of o-,m-,and p-chlorotoluene at 193 nm under collision-free conditions has been studied using multimass ion imaging techniques.In addition to the Cl atom elimination,photofragments corresponding to the reactions of C_6H_4ClCH_3->C_6H_4ClCH_2 + H and C_6H_4ClCH_3 ->C_6H_4Cl+CH_3 were observed.Dissociation rates and fragment translational energy distributions were measured.A comparison with RRKM calculation has been made te possble dissociation mechanism was discussed.

机译：利用多质量离子成像技术研究了邻，间和对氯甲苯在无碰撞条件下在193 nm处的光解离。除Cl原子消除外，与C_6H_4ClCH_3-> C_6H_4ClCH_2 + H和观察到C_6H_4ClCH_3-> C_6H_4Cl + CH_3。测量了解离速率和碎片平移能分布。与RRKM计算进行了比较，探讨了可能的解离机理。

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《The Journal of Chemical Physics》 |2003年第15期|共4页
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Ming-Fu Lin; Cheng-Liang huang; Vadim V.Kislov; A.M.Mebel; Yuan T.Lee; Chi-Kung Ni;
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1. H and CH_3 eliminations in the photodissociation of chlorotoluene [J] . Ming-Fu Lin, Cheng-Liang huang, Vadim V.Kislov, The Journal of Chemical Physics . 2003,第15期

机译：氯甲苯光解中的H和CH_3消除
2. The Two Competitive Photodissociation Channels in Cyano Carbonyls (NCC(O)X, X = CH_3, CH(CH_3)_2, C(CH_3)_3, OCH_3) at 193 nm. A Study by Photofragment Translational Energy Spectroscopy [J] . Frulan Alan The journal of physical chemistry, A. Molecules, spectroscopy, kinetics, environment, & general theory . 2000,第9期

机译：氰基羰基中的两个竞争性光解离通道（NCC（O）X，X = CH_3，CH（CH_3）_2，C（CH_3）_3，OCH_3）。光碎裂转化能谱研究
3. Quantum-mechanical tunneling in the H_2 elimination from 2,3-dimethylbutane cation: (CH_3)_2CHCH(CH_3)_2~+ → (CH_3)_2C=C(CH_3)_2~+ + H_2. An ab initio molecular orbital study [J] . Yuzuru Kurosaki, Toshiyuki Takayanagi, Tetsuo Miyazaki Journal of Molecular Structure. Theochem: Applications of Theoretical Chemistry to Organic, Inorganic and Biological Problems . 1998,第1a3期

机译：从2,3-二甲基丁烷阳离子中H_2消除的量子力学隧穿：（CH_3）_2CHCH（CH_3）_2〜+→（CH_3）_2C = C（CH_3）_2〜+ + H_2。从头算分子轨道研究
4. CH_3 Detection in Flames Using Photodissociation-Induced Fluorescence [C] . P.Desgroux, L.Gasnot, B.Crunelle, International symposium on combustion . 1996

机译：使用光解离诱导荧光检测火焰中的CH_3
5. The kinetics and mechanisms of chlorine atom reactions with chlorotoluenes and fluorotoluenes. [D] . Haddad, Nassim. 2013

机译：氯原子与氯甲苯和氟甲苯反应的动力学和机理。
6. Characterization of Hydrogen Bonding Motifs in Proteins: Hydrogen Elimination Monitoring by Ultraviolet Photodissociation Mass Spectrometry [O] . Lindsay J. Morrison, Wenrui Chai, Jake A. Rosenberg, -1

机译：蛋白质中氢键基序的表征：紫外光解离质谱法监测氢的消除
7. H and CH3 eliminations in the photodissociation of chlorotoluene [O] . Ming-Fu Lin 2011

机译：氯甲苯光解中的H和CH3消除
8. Photodissociation studies of the chlorotoluenes at 193 nm and 248 nm. [R] . Helfand, M. S. 1989

机译：氯酚在193 nm和248 nm处的光解离研究。

H and CH_3 eliminations in the photodissociation of chlorotoluene

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