Photodissociation of vibrationally excited ammonia:rotational excitation in the NH_2 product

Andreas Bach; J.Matthew Hutchison; Robert J.Holiday; F.Fleming Crim

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Photodissociation of vibrationally excited ammonia:rotational excitation in the NH_2 product

机译：振动激发氨的光解离：NH_2产物中的旋转激发

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The first singlet excited state of ammonia is a model system for nonadiabtic photodissociation dynamics. The A state of NH_3 is quasibound with a barrier in the exit channel leading to the products H+NH_2. The competition between noadiabatic and adiabatic dissociation governs the branching between the ground the first electronic excited states of the NH_2 fragment in the region bebyond the barrier on the excited state.

机译：氨的第一个单重态激发态是非绝热光解动力学的模型系统。 NH_3的A状态在出口通道中与势垒准结合，从而导致产物H + NH_2。绝热和绝热解离之间的竞争控制着NH_2片段的第一电子激发态在该激发态势垒附近的区域之间的分支。

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《The Journal of Chemical Physics》 |2003年第15期|共2页
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Andreas Bach; J.Matthew Hutchison; Robert J.Holiday; F.Fleming Crim;
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1. Photodissociation of vibrationally excited ammonia:rotational excitation in the NH_2 product [J] . Andreas Bach, J.Matthew Hutchison, Robert J.Holiday, The Journal of Chemical Physics . 2003,第15期

机译：振动激发氨的光解离：NH_2产物中的旋转激发
2. Bond-selective photodissociation of partially deuterated ammonia molecules: Photodissociations of vibrationally excited NHD_2 in the 5upsilon_(NH) state and NH_2D in the 5upsilon_(ND) state [J] . Hiroshi Akagi, Keiichi Yokoyama, Atsushi Yokoyama The Journal of Chemical Physics . 2004,第10期

机译：部分氘代氨分子的键选择光解离：振动激发的NHD_2在5upsilon_（NH）状态和NH_2D在5upsilon_（ND）状态下的光解离
3. Bond-selective photodissociation of partially deuterated ammonia molecules: Photodissociations of vibrationally excited NHD_2 in the 5upsilon_(NH) state and NH_2D in the 5upsilon_(ND) state [J] . Hiroshi Akagi, Keiichi Yokoyama, Atsushi Yokoyama The Journal of Chemical Physics . 2004,第10期

机译：部分氘代氨分子的键选择光解离：振动激发的NHD_2在5upsilon_（NH）状态和NH_2D在5upsilon_（ND）状态下的光解离
4. Direct measurements of state-to-state rotational and vibrational energy transfer in highly vibrational excited acetylene: vibrational overtone excitation--LIF detection [C] . Joseph D. Tobiason, Univ. of Wisconsin/Madison, Madison, Conference on laser techniques for state-selected and state-to-state chemistry . 1993

机译：高振动激发乙炔中状态到状态的旋转和振动能量传递的直接测量：振动泛音激发-LIF检测
5. Photodissociation dynamics and spectroscopy of small, isolated, vibrationally excited molecules: Ammonia and methanol [D] . Hutchison, J. Matthew 2004

机译：小的，分离的，振动激发的分子：氨和甲醇的光解离动力学和光谱
6. Effects of vibrational excitation on the F + H2O → HF + OH reaction: dissociative photodetachment of overtone-excited F–H–OH– [O] . Amelia W. Ray, Jianyi Ma, Rico Otto, 2017

机译：振动激发对F + H2O→HF + OH反应的影响：泛音激发的F–H–OH –的解离光解
7. Polar- and Azimuth-Angle-Dependent Rotational and Vibrational Excitation of Desorbing Product CO2 in CO Oxidation on Palladium Surfaces [O] . Yamanaka Toshiro, Matsushima Tatsuo 2008

机译：钯表面上CO氧化中解吸产物CO2的极性和方位角相关的旋转和振动激发
8. Vibrational-Rotational Excitation: Chemical Reactions of Vibrationally Excited Molecules [R] . Moore, C. B., Smith, I. W. M. 1979

机译：振动 - 旋转激发：振动激发分子的化学反应

Photodissociation of vibrationally excited ammonia:rotational excitation in the NH_2 product

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