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Glass and polycrystal state in a lattice spin model

机译:晶格自旋模型中的玻璃和多晶态

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We numerically study a nondisordered lattice spin system with afirst order liquid-crystal transition,as a model for supercooled liquids and glasses. Below the melting temperature the sysem can be kept in the metastable liquid phase,andit displays a dynamic phenomenology analogous to fragile supercooled liquids,with stretched exponential relaxation,power law increase of the relaxation time,and hig fragility index. At an effective spindal temperature T_(sp) the liquid properties cannot be extrapolated,in line with Kauzmann's scenarion of a lower metastability limit of supercooled liquids as a solution of Kauzmann's paradox. The off-equilibrium dynamics below T_(sp) corresponds to fast nucleation of small,but stable,crystal droplets,followed by extremetly slow grower the temperature,this crystal-growth phase is indistinguish able from an off-equilibrium glass,both from a structurla and a dynamical point of view:crystal growth has not advanced enough to be structurally detectable,and a violation of the fluctuation-dissipation theorem (FDT) typical of structural glasses is observed. On the other hand,for longer times crystallization reaches a threshold beyond which crystal domiains are easily identified,and FDT violation becomes compatible with ordinary domain growth.
机译:作为一类过冷液体和玻璃的模型,我们数值研究了具有一阶液晶跃迁的无序晶格自旋系统。在熔化温度以下,该体系可以保持在亚稳态液相中,并且表现出类似于易碎的过冷液体的动态现象,具有伸长的指数弛豫,弛豫时间的幂律增加和高脆性指数。在有效的旋流温度T_(sp)下,无法推断液体性质,这与Kauzmann提出的过冷液体亚稳态极限较低的情况(作为Kauzmann悖论的解决方案)一致。低于T_(sp)的失衡动力学对应于小的但稳定的晶体液滴的快速成核作用,随后温度极其缓慢地增长,该晶体生长相与失衡的玻璃,结构均不明显。从动力学的角度来看:晶体的生长尚未进行到足以在结构上检测到的程度,并且观察到违反了结构玻璃的典型波动耗散定理(FDT)。另一方面,较长时间的结晶达到一个阈值,超过该阈值很容易识别晶体多巴胺,并且违反FDT变得与普通畴生长相容。

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