Determination of the conditional dimerization constants from the sound velocity data in binary liquid mixtures containing an associating solute and a nonassociating solvent

Glinski J

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Determination of the conditional dimerization constants from the sound velocity data in binary liquid mixtures containing an associating solute and a nonassociating solvent

机译：从包含缔合溶质和非缔合溶剂的二元混合液中的声速数据确定条件二聚常数

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摘要

A new model of calculating the self-association constants in mixtures of two liquids, an associating solute and a nonassociating solvent, is proposed and analyzed. The model assumes additivity of the time of transmission of the acoustic signal with the volume fractions of the components of the mixture. The model was tested for different systems, showing that the results are reliable and close to expectations. The presented attempt seems to be an interesting alternative in interpreting the experimental results of sound velocity measurements in liquid mixtures.

机译：提出并分析了一种计算两种液体（缔合溶质和非缔合溶剂）混合液中自缔合常数的新模型。该模型假设声音信号的传输时间与混合物成分的体积分数相加。该模型针对不同的系统进行了测试，表明结果可靠且接近预期。在解释液体混合物中声速测量的实验结果时，提出的尝试似乎是一个有趣的选择。

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《The Journal of Chemical Physics》 |2005年第7期|共6页
作者
Glinski J;
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正文语种 eng
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ISENTROPIC COMPRESSIBILITIES; INTERMOLECULAR INTERACTIONS; MOLECULAR-INTERACTIONS; REFRACTIVE-INDEXES; ULTRASONIC SPEEDS; ALCOHOLS; HEPTANE; 1-OCTANOL; HEXANE; TEMPERATURE;

机译：等熵可压缩性;分子间相互作用;分子相互作用;折光指数;超声速;醇;庚烷;1-辛醇;己烷;温度;

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1. Determination of the conditional dimerization constants from the sound velocity data in binary liquid mixtures containing an associating solute and a nonassociating solvent [J] . Glinski J The Journal of Chemical Physics . 2005,第7期

机译：从包含缔合溶质和非缔合溶剂的二元混合液中的声速数据确定条件二聚常数
2. Determination of the conditional dimerization constants from the sound velocity data in binary liquid mixtures containing an associating solute and a nonassociating solvent [J] . Jacek Gliriski The Journal of Chemical Physics . 2005,第7期

机译：从包含缔合溶质和非缔合溶剂的二元混合液中的声速数据确定条件二聚常数
3. Determination of the conditional association constants from the sound velocity data in binary liquid mixtures [J] . Jacek Glinski The Journal of Chemical Physics . 2003,第5期

机译：根据二元液体混合物中的声速数据确定条件缔合常数
4. THERMODYNAMIC CONSISTENCY TESTS FOR PHASE EQUILIBRIUM IN LIQUID SOLUTE+SUPERCRITICAL SOLVENT MIXTURES [C] . Jose O. Valderrama, Victor H. Alvarez International Symposium on Supercritical Fluids Tome 2: SCF Properties Reactions; 20030428-20030430; Versailles; FR . 2003

机译：液相溶液+超临界溶剂混合物中相平衡的热力学一致性测试
5. AQUEOUS AND SOLVENT EXTRACTION CHEMISTRY OF SOME OF THE ACTINIDE ELEMENTS, DETERMINATION OF THE INSTABILITY CONSTANTS AND CONDITIONAL EQUILIBRIUM CONSTANTS OF SOME COMPLEXES OF NEPTUNIUM AND PLUTONIUM [D] . EL-EZABY, MOHAMED SAMIR ABD EL-AZIZ. 1967

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6. Binary Solvents Dispersive Liquid—Liquid Microextraction (BS-DLLME) Method for Determination of Tramadol in Urine Using High-Performance Liquid Chromatography [O] . Vahid Kiarostami, Mohamad-Reza Rouini, Razieh Mohammadian, 2014

机译：高效液相色谱法测定尿液中曲马多的二元溶剂分散液-液相微萃取（BS-DLLME）方法
7. Thermochemical Investigations of Gas-Liquid Chromatography. Partition Coefficients of Inert Solutes on Self-Associating Binary Solvent Mixtures [O] . Acree, William E. (William Eugene) 1982

机译：气液色谱的热化学研究。自缔合二元溶剂混合物中惰性溶质的分配系数
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机译：轻溶剂中重烃混合物的固 - 液平衡数据的测定

Determination of the conditional dimerization constants from the sound velocity data in binary liquid mixtures containing an associating solute and a nonassociating solvent

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