Rotationally selected product pair correlation:F+CD_4- DF(v')+ CD_3(v_2=0 ancl 2,N)

Jingang Zhou; Weicheng Shiu; Jim J.Lin; Kopin Liu

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Rotationally selected product pair correlation:F+CD_4- DF(v')+ CD_3(v_2=0 ancl 2,N)

机译：旋转选择的乘积对相关性：F + CD_4-> DF（v'）+ CD_3（v_2 = 0 ancl 2，N）

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The product pair correlation of the title reaction was measured with rotational selection for both the vibrationally ground CD_3(v=0)and umbrella-excited CD_3(v_2=2)products.A striking linear relationship was found between the rotational energy of the selected CD_3 product and the correlated kinetic energy release(or the average vibrational energy of the DF coproduct).Such a linearly correlated(or anticorrelated)dependence appears to be stronger for CD_3(v_2=2,N)than for CD_3(V=0,N).The mechanistic implication of the observation is that the rotational motion N of the CD_3 product tends to lie antiparallel to the orbital angular momentum 1'of the two departing products.The dependency on the K quantum number-the projection of N on the top axis-is,on the other hand,less significant yet noticeable.

机译：振动研磨的CD_3（v = 0）和伞激发的CD_3（v_2 = 2）产物的旋转选择测量了标题反应的产物对相关性，发现选定CD_3的旋转能之间存在惊人的线性关系CD_3（v_2 = 2，N）的线性相关（或反相关）依赖性似乎比CD_3（V = 0，N）的线性相关（或反相关）依赖性更强观察到的机理是CD_3乘积的旋转运动N趋于与两个离去乘积的轨道角动量1'反平行。对K量子数的依赖性-N在顶部的投影另一方面，轴是不重要但值得注意的。

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《The Journal of Chemical Physics》 |2006年第10期|共9页
作者
Jingang Zhou; Weicheng Shiu; Jim J.Lin; Kopin Liu;
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1. Rotationally selected product pair correlation:F+CD_4- DF(v')+ CD_3(v_2=0 ancl 2,N) [J] . Jingang Zhou, Weicheng Shiu, Jim J.Lin, The Journal of Chemical Physics . 2006,第10期

机译：旋转选择的乘积对相关性：F + CD_4-> DF（v'）+ CD_3（v_2 = 0 ancl 2，N）
2. Imaging the effects of bend-excitation in the F + CD_4(v _b=0,1) → DF(v) + CD_3(v_2=1,2) reactions [J] . Wang F., Liu K. The journal of physical chemistry, A. Molecules, spectroscopy, kinetics, environment, & general theory . 2013,第36期

机译：成像F + CD_4（v _b = 0,1）→DF（v）+ CD_3（v_2 = 1,2）反应中的弯曲激发效应
3. Mode correlation of product pairs in the reaction OH + CD_4- HOD + CD_3 [J] . Bailin Zhang, Weicheng Shiu, Jim J.Lin, The Journal of Chemical Physics . 2005,第13期

机译：反应OH + CD_4-> HOD + CD_3中产物对的模式相关
4. Effect of Reagent Vibrational Excitation on Product Rotational Polarization in Reactions Li + DF (v=0-3, j=0)→ LiF(v', j') + D [C] . Jie Cheng, Xian-Fang Yue International Conference on Chemical Engineering and Advanced Materials . 2013

机译：试剂振动激发对反应中产物旋转极化的影响Li + DF（V = 0-3，J = 0）→LiF（V'，J'）+ D.
5. Radical Pairs with Rotational Fluidity in the Photochemical Reaction of Acetophenone and Cyclohexane in the Zeolite NaY: A 13C CPMAS NMR and Product Analysis Study [O] . Ammee Amboya, Tina Nguyen, Hien T. Huynh, -1

机译：与旋转流动性自由基对在苯乙酮和环己烷在沸石NaY分子筛的光化学反应：一13C Cpmas NmR和产品分析研究
6. Exponential dependence of the nuclear moment of inertia on pairing correlation and the pairing stretch model for nuclear rotation [O] . Chin W. Ma, John O. Rasmussen 1974

机译：惯性核动力对核旋转配对相关性与配对拉伸模型的指数依赖性

Rotationally selected product pair correlation:F+CD_4- DF(v')+ CD_3(v_2=0 ancl 2,N)

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