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首页> 外文期刊>The Journal of Chemical Physics >Excitation,dynamics,and control of rotationaiiy autoionizing Rydberg states of H2
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Excitation,dynamics,and control of rotationaiiy autoionizing Rydberg states of H2

机译:激发,动力学和自转控制H2的Rydberg态的自转

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摘要

The dynamics of rotationaiiy autoionizing Rydberg states of molecular hydrogen is investigated using a time-dependent extension of multichannel quantum defect theory,in which the time-dependent wave packets are constructed using first-order perturbation theory.An analytical expression for the complex excitation function for a sequence of Gaussian excitation pulses is derived and then employed to investigate the influence of pairs of pulses with well-defined phase differences on the decay dynamics and final-state composition.
机译:利用多通道量子缺陷理论的时变扩展研究了分子氢的Rydberg自旋自旋动力学,利用一阶扰动理论构造了时变波包。推导出一系列高斯激发脉冲,然后将其用于研究具有明确定义的相位差的成对脉冲对衰减动力学和最终状态组成的影响。

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