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Theoretical study on the sound absorption of electrolytic solutions.I.Theoretical formulation

机译:电解质溶液吸声的理论研究I.理论公式

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A theory is formulated that describes the sound absorption of electrolytic solutions due to the relative motion of ions,including the formation of ion pairs.The theory is based on the Kubo-Green formula for the bulk viscosity.The time correlation function of the pressure is projected onto the bilinear product of the density modes of ions.The time development of the product of density modes is described by the diffusive limit of the generalized Langevin equation,and approximate expressions for the three- and four-body correlation functions required are given with the hypernetted-chain integral equation theory.Calculations on the aqueous solutions of model electrolytes are performed.It is demonstrated that the theory describes both the activated barrier crossing between contact and solvent-separated ion pairs and the Coulombic correlation between ions.
机译:建立了一个描述由于离子的相对运动而引起的电解液吸声的理论,包括离子对的形成,该理论基于Kubo-Green公式的体积粘度,压力的时间相关函数为通过广义朗格文方程的扩散极限来描述密度模积的时间发展,并给出了所需的三体和四体相关函数的近似表达式。对模型电解质的水溶液进行了计算。结果表明,该理论既描述了接触和溶剂分离的离子对之间的活化势垒穿越,又描述了离子之间的库仑相关性。

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