首页> 外文期刊>The Journal of Chemical Physics >The low frequency phonons dynamics in supercooled LiCI, 6H_2O
【24h】

The low frequency phonons dynamics in supercooled LiCI, 6H_2O

机译:过冷的LiCI,6H_2O中的低频声子动力学

获取原文
获取原文并翻译 | 示例
           

摘要

We report the results of a series of ultrasound, Brillouin scattering, and optical heterodyne detectedtransient grating experiments performed on a LiCl, 6H_2Osolution from room temperature down tothe vicinity of its liquid-glass transition, T_g~138 K. Down toT~215K, the supercooled liquidhas a behavior similar to what is expected for supercooled water: its zero frequency sound velocity,C_0, continuously decreases while the corresponding infinite frequency velocity, Coo,sharplyincreases, reflecting the increasing importance of H bonding when temperature is lowered. Below215 K, specific aspects of the solution, presumably related to the role of the Li~+and Cl~-ions, modifythe thermal behavior of C_0, while a βrelaxation process also appears and couples to the soundpropagation. The origin of those two effects is briefly discussed.
机译:我们报告了一系列超声波,布里渊散射和光学外差检测的结果,这些检测是在LiCl,6H_2O溶液从室温到液玻璃化转变温度T_g〜138 K附近进行的瞬态光栅实验。液体的行为类似于过冷水的行为:其零频率声速C_0持续降低,而相应的无限频率声速Coo急剧增加,反映出降低温度时H键的重要性日益提高。在215 K以下,该解决方案的特定方面,可能与Li〜+和Cl〜离子的作用有关,改变了C_0的热行为,同时还出现了β松弛过程并与声音传播耦合。简要讨论了这两种作用的起源。

著录项

相似文献

  • 外文文献
  • 中文文献
  • 专利
获取原文

客服邮箱:kefu@zhangqiaokeyan.com

京公网安备:11010802029741号 ICP备案号:京ICP备15016152号-6 六维联合信息科技 (北京) 有限公司©版权所有
  • 客服微信

  • 服务号