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Communication: Molecular gears

机译:交流:分子齿轮

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The H-1 nuclear magnetic resonance spectrum of hexamethylbenzene orientationally ordered in the nematic liquid crystal ZLI-1132 is analysed using covariance matrix adaptation evolution strategy. The spectrum contains over 350 000 lines with many overlapping transitions, from which four independent direct dipolar couplings are obtained. The rotations of the six methyl groups appear to be correlated due to mutual steric hindrance. Adjacent methyl groups show counter-rotating or geared motion. Hexamethylbenzene thus behaves as a molecular hexagonal gear. Published by AIP Publishing.
机译:使用协方差矩阵自适应演化策略分析了向列液晶ZLI-1132中取向有序的六甲基苯的H-1核磁共振谱。该频谱包含超过35万条具有许多重叠过渡的谱线,从中可以获得四个独立的直接偶极耦合。由于相互的空间位阻,六个甲基的旋转似乎是相关的。相邻的甲基显示反向旋转或齿轮运动。六甲基苯因此表现为分子六角齿轮。由AIP Publishing发布。

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