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Adsorption of highly charged Gaussian polyelectrolytes onto oppositely charged surfaces

机译:高电荷的高斯聚电解质吸附在带相反电荷的表面上

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摘要

In many biological processes highly charged biopolymers are adsorbed onto oppositely charged surfaces of macroions and membranes. They form strongly correlated structures close to the surface which cannot be explained by the conventional Poisson-Boltzmann theory. In this work strong coupling theory is used to study the adsorption of highly charged Gaussian polyelectrolytes. Two cases of adsorptions are considered, when the Gaussian polyelectrolytes are confined (a) by one charged wall, and (b) between two charged walls. The effects of salt and the geometry of the polymers on their adsorption-depletion transitions in the strong coupling regime are discussed. (C) 2016 AIP Publishing LLC.
机译:在许多生物过程中,高电荷的生物聚合物被吸附到大分子和膜的带相反电荷的表面上。它们在表面附近形成强相关的结构,这是常规的泊松-玻尔兹曼理论无法解释的。在这项工作中,使用强耦合理论来研究高电荷高斯聚电解质的吸附。当高斯聚电解质被限制在(a)一个带电壁和(b)在两个带电壁之间时,考虑了两种吸附情况。讨论了盐和聚合物的几何形状对其在强偶联体系中的吸附-耗尽转变的影响。 (C)2016 AIP出版有限责任公司。

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