High-Resolution Ion-Imaging Studies of the Photodissociation of the BrCl~+ Cation

N.Hendrik Nahler; Olivier P.J.Vieuxmaire; Josephine R.Jones

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High-Resolution Ion-Imaging Studies of the Photodissociation of the BrCl~+ Cation

机译：BrCl〜+阳离子光解离的高分辨率离子成像研究

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The photofragmentation of state-selected BrCl~+ cations has been investigated by velocity-map ion-imaging methods.Detailed analyses of the ~(79)Br~+ fragment velocities lead to the most precise values yet reported for (i) the spin-orbit coupling constant for the X~2II state,A - -2070 +- 4 cm~(-1);(ii) the bond dissociation energies of both states of ~(79)Br~(35)Cl~+,25019 ± 4 cm~(-1) (X~2II_(3/2)) and 22949 +_ 2 cm~(-1) (X~2II_(1/2));and (iii) the adiabatic ionization thresholds for forming ~(79)Br~(35)Cl~+ parent ions in their X~2II_(3/2) and X~2II_(1/2) states,88292 +-6 and 90362 +- 4 cm~(-1),respectively.

机译：已经通过速度图离子成像方法研究了状态选择的BrCl〜+阳离子的光碎化。〜（79）Br〜+碎片速度的详细分析导致了迄今为止最精确的值（i）自旋- X〜2II态的轨道耦合常数，A--2070 +-4 cm〜（-1）;（ii）〜（79）Br〜（35）Cl〜+两种态的键解离能，25019± 4 cm〜（-1）（X〜2II_（3/2））和22949 + _ 2 cm〜（-1）（X〜2II_（1/2））;以及（iii）形成〜的绝热电离阈值（79）Br〜（35）Cl〜+母离子处于X〜2II_（3/2）和X〜2II_（1/2）态88292 + -6和90362 +-4 cm〜（-1），分别。

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《The journal of physical chemistry, A. Molecules, spectroscopy, kinetics, environment, & general theory》 |2004年第39期|共7页
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N.Hendrik Nahler; Olivier P.J.Vieuxmaire; Josephine R.Jones;
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1. High-Resolution Ion-Imaging Studies of the Photodissociation of the BrCl~+ Cation [J] . N.Hendrik Nahler, Olivier P.J.Vieuxmaire, Josephine R.Jones The journal of physical chemistry, A. Molecules, spectroscopy, kinetics, environment, & general theory . 2004,第39期

机译：BrCl〜+阳离子光解离的高分辨率离子成像研究
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7. Photodissociation dynamics of tert-butylnitrite following excitation to the S(1) and S(2) states. A study by velocity-map ion-imaging and 3D-REMPI spectroscopy [O] . Wenge, Andreas M, Schmaunz, Andreas, Kensy, Uwe, 2012

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High-Resolution Ion-Imaging Studies of the Photodissociation of the BrCl~+ Cation

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