Infrared hole burning and conformational change in a borane-ammonia complex

Endicott CA; Strauss HL; Hughes CC; Trauner D

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Infrared hole burning and conformational change in a borane-ammonia complex

机译：硼烷-氨络合物中的红外孔燃烧和构象变化

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The N-D stretching region in the infrared spectrum of the ammonia complex of tris-(2-methoxymethylphenol)-borane containing one D atom has been examined. The N-D bands have been hole burned, and the resulting spectra reveal the reorientation kinetics of the ammonia. The ammonia is hydrogen bonded with the bond distances and reorientation barrier typical of other compounds. The N-D stretching frequencies are higher than those of comparison compounds.

机译：研究了含有一个D原子的三-（2-甲氧基甲基苯酚）-硼烷的氨络合物的红外光谱中的N-D拉伸区域。 N-D谱带已被空穴燃烧，所得光谱揭示了氨的重新取向动力学。氨与其他化合物所具有的键距和重新取向势垒氢键合。 N-D拉伸频率高于比较化合物。

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《The journal of physical chemistry, A. Molecules, spectroscopy, kinetics, environment, & general theory》 |2005年第34期|共4页
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Endicott CA; Strauss HL; Hughes CC; Trauner D;
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机译：盐;

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1. Infrared hole burning and conformational change in a borane-ammonia complex [J] . Endicott CA, Strauss HL, Hughes CC, The journal of physical chemistry, A. Molecules, spectroscopy, kinetics, environment, & general theory . 2005,第34期

机译：硼烷-氨络合物中的红外孔燃烧和构象变化
2. Conformation of Alkali Metal Ion-Benzo-12-Crown-4 Complexes Investigated by UV Photodissociation and UV-UV Hole-Burning Spectroscopy [J] . Inokuchi Yoshiya, Nakatsuma Maki, Kida Motoki, The journal of physical chemistry, A. Molecules, spectroscopy, kinetics, environment, & general theory . 2016,第32期

机译：紫外光解离和紫外-紫外孔烧光谱法研究的碱金属离子-Benzo-12-Crown-4配合物的构象
3. Infrared hole burning of crown ether 18-c-6 ammonium ion complexes [J] . Endicott C, Strauss HL The journal of physical chemistry, A. Molecules, spectroscopy, kinetics, environment, & general theory . 2007,第7期

机译：冠醚18-c-6铵离子络合物的红外孔燃烧
4. Infrared Picosecond Hole-burning Study On The Correlation Properties Of Hydrogen Bonds [C] . Bakker, H.J., Bonn, . 2001

机译：红外皮秒空穴燃烧对氢键相关性的研究
5. Investigating molecular interactions and conformational reorientation in amino acids and fatty acids: Infrared spectral hole burning and vibrational spectroscopy [D] . Li, Hung-Wen 2000

机译：研究氨基酸和脂肪酸中的分子相互作用和构象重排：红外光谱孔燃烧和振动光谱
6. Real-time observation of conformational fluctuations in Zn-substituted myoglobin by time-resolved transient hole-burning spectroscopy. [O] . Y Shibata, A Kurita, T Kushida 1998

机译：通过时间分辨瞬态空穴燃烧光谱法实时观察锌取代的肌红蛋白中构象的波动。
7. Infrared Hole Burning and Conformational Change in a Borane-Ammonia Complex [O] . Christopher Endicott Herbert, Herbert L. Strauss, Chambers C. Hughes, 2005

机译：硼烷-氨络合物中的红外孔燃烧和构象变化
8. Persistent Changes in the FIR Spectrum of KI: NO(-2) Produced by IR (Infrared) Vibrational Hole Burning [R] . Ambrose, W. P., Sievers, A. J. 1988

机译：红外（红外）振动孔燃烧产生的KI：NO（-2）的FIR谱的持续变化

Infrared hole burning and conformational change in a borane-ammonia complex

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