Fluorinated Fullerenes:Sources of Donor-Acceptor Dyads with [18]Trannulene Acceptors for Energy-and Electron-Transfer Reactions

Dirk M.Guldi; Massimo Marcaccio; Francesco Paolucci; Demis Paolucci; Jeff Ramey

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Fluorinated Fullerenes:Sources of Donor-Acceptor Dyads with [18]Trannulene Acceptors for Energy-and Electron-Transfer Reactions

机译：氟化富勒烯：具有[18]戊二烯受体的给体-受体二元化合物的能量和电子转移反应来源

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Fine-tuned control over the donor strength in a series of trannulenes-based donor-acceptor ensembles is used to alter the deactivation path of the photoexcited-state chromophore and to modulate the rates of intramolecular electron transfer.For the first time,a detailed analysis of emission spectra,time-dependent spectroscopic measurements,and electrochemistry prove spectroscopically and kinetically that trannulenes can serve,in a manner similar to C_(60)and C_(60)monoadducts,as both electron and also as energy acceptor in donor-acceptor ensembles,producing widely different electron-transfer regimes.This investigation also shows that the integration of trannulenes,as a versatile electron-acceptor building block,consistently produces charge recombination in the inverted Marcus region.

机译：在一系列基于对苯二酚的供体-受体集成体中，对供体强度的精细控制可用于改变光激发态发色团的失活路径并调节分子内电子转移的速率。这是首次，详细分析发射光谱，随时间变化的光谱测量结果以及电化学反应在光谱学和动力学方面证明了对戊二烯可以以类似于C_（60）和C_（60）单加合物的方式用作电子和供体-受体集合体中的能量受体这项研究还表明，作为一种通用的电子受体构建体，对苯二酚的整合始终在倒置的马库斯区产生电荷复合。

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《The journal of physical chemistry, A. Molecules, spectroscopy, kinetics, environment, & general theory》 |2005年第43期|共8页
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Dirk M.Guldi; Massimo Marcaccio; Francesco Paolucci; Demis Paolucci; Jeff Ramey;
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1. Fluorinated Fullerenes:Sources of Donor-Acceptor Dyads with [18]Trannulene Acceptors for Energy-and Electron-Transfer Reactions [J] . Dirk M.Guldi, Massimo Marcaccio, Francesco Paolucci, The journal of physical chemistry, A. Molecules, spectroscopy, kinetics, environment, & general theory . 2005,第43期

机译：氟化富勒烯：具有[18]戊二烯受体的给体-受体二元化合物的能量和电子转移反应来源
2. Photoinduced electron-transfer dynamics and long-lived CS states of donor-acceptor linked dyads and a triad containing a gold porphyrin in nonpolar solvents [J] . Ohkubo K, Sintic PJ, Tkachenko NV, Chemical Physics: A Journal Devoted to Experimental and Theoretical Research Involving Problems of Both a Chemical and Physical Nature . 2006,第1期

机译：供体-受体连接的二元组和含金卟啉的三元组在非极性溶剂中的光诱导电子转移动力学和长寿命CS态
3. Effects of a Central Atom and Peripheral Substituents on Photoinduced Electron Transfer in the Phthalocyanine-Fullerene Donor-Acceptor Solution-Processable Dyads [J] . Ovchenkova Ekaterina N., Bichan Natatiya G., Tsaturyan Arshak A., The journal of physical chemistry, C. Nanomaterials and interfaces . 2020,第7期

机译：中央原子和外周取代基对酞菁 - 富勒烯供体溶液可加工二元的光致电子转移的影响
4. Synthesis of 18pi-Annulenic Fluorofullerenes (Trannulenes):A new generation of donor-acceptor materials. [C] . Glenn A.Burley, Anthony G.A vent, Olga V.Boltalina, The Meeting of the Electrochemical Society . 2003

机译：18PI-含氧氟尿嘧啶（Trannulenes）的合成：新一代供体受体材料。
5. Mechanistic studies on electron-transfer reactions from zero-valent ruthenium complexes to organic or inorganic acceptors: Isolation, characterization, and reactivity of the products obtained upon oxidation. [D] . Skoog, Steven John. 1997

机译：从零价钌络合物到有机或无机受体的电子转移反应的机理研究：氧化所得产物的分离，表征和反应性。
6. Time-Dependent Solid State Polymorphism of a Series of Donor-Acceptor Dyads [O] . Cameron Peebles, Paul M. Alvey, Vincent Lynch, -1

机译：一系列供体-受体二元组的时间依赖性固态多态性
7. Ruthenium(II) Coordination Chemistry of a Fused Donor-Acceptor Ligand: Synthesis, Characterization, and Photoinduced Electron-Transfer Reactions of [{Ru(bpy)2}n(TTF-ppb)](PF6)2n (n = 1, 2) [O] . Goze, Christine, Dupont, Nathalie, Beitler, Elvira, 2008

机译：熔融的供体-受体配体的钌（II）配位化学：[{Ru（bpy）2} n（TTF-ppb）]（PF6）2n的合成，表征和光致电子转移反应（n = 1，2 ）

Fluorinated Fullerenes:Sources of Donor-Acceptor Dyads with [18]Trannulene Acceptors for Energy-and Electron-Transfer Reactions

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