Reply to 'Comment on the 'Thermodynamic Dissociation Constant of the Bisulfate Ion from Raman and Ion Interaction Modeling Studies of Aqueous Sulfuric Acid at Low Temperatures''

D.A.Knopf; B.P.Luo; U.K.Krieger; Thomas Koop

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Reply to 'Comment on the 'Thermodynamic Dissociation Constant of the Bisulfate Ion from Raman and Ion Interaction Modeling Studies of Aqueous Sulfuric Acid at Low Temperatures''

机译：答复“关于'拉曼硫酸氢根离子的热力学解离常数和低温下硫酸水溶液的离子相互作用模拟研究”的评论”

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In their comment,Clegg and Brimblecombe question the validity of both the data and the model of Knopf et al.and conclude that their own "AIM appears to yield more accurate predictions of water and H_2SO_4 activities under most conditions,including low temperatures".In the following,we respond to these criticisms and discuss why we do not agree with these conclusions.

机译：在他们的评论中，Clegg和Brimblecombe质疑数据和Knopf等人模型的有效性，并得出结论，他们自己的“ AIM似乎能够在大多数条件下，包括低温下，更准确地预测水和H_2SO_4的活动”。接下来，我们对这些批评做出回应，并讨论为什么我们不同意这些结论。

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《The journal of physical chemistry, A. Molecules, spectroscopy, kinetics, environment, & general theory》 |2005年第11期|共3页
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D.A.Knopf; B.P.Luo; U.K.Krieger; Thomas Koop;
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1. Reply to "Comment on the 'Thermodynamic Dissociation Constant of the Bisulfate Ion from Raman and Ion Interaction Modeling Studies of Aqueous Sulfuric Acid at Low Temperatures'" [J] . D.A.Knopf, B.P.Luo, U.K.Krieger, The journal of physical chemistry, A. Molecules, spectroscopy, kinetics, environment, & general theory . 2005,第11期

机译：答复“关于'拉曼硫酸氢根离子的热力学解离常数和低温下硫酸水溶液的离子相互作用模拟研究”的评论”
2. Comment on the "Thermodynamic Dissociation Constant of the Bisulfate Ion from Raman and Ion Interaction Modeling Studies of Aqueous Sulfuric Acid at Low Temperatures" [J] . Simon L.Clegg, Peter Brimblecombe The journal of physical chemistry, A. Molecules, spectroscopy, kinetics, environment, & general theory . 2005,第11期

机译：评论“低温下硫酸水溶液中硫酸氢根离子的热力学解离常数和离子相互作用模型研究”
3. Thermodynamic Dissociation Constant of the Bisulfate Ion from Raman and Ion Interaction Modeling Studies of Aqueous Sulfuric Acid at Low Temperatures [J] . D. A. Knopf, B. P. Luo, U. K. Krieger, The journal of physical chemistry, A. Molecules, spectroscopy, kinetics, environment, & general theory . 2003,第21期

机译：拉曼硫酸氢根离子的热力学解离常数和硫酸水溶液在低温下的离子相互作用模型研究
4. ~(13)C-NMR study of acid dissociation constant (pKa) effects on the CO2 absorption and regeneration of aqueous alkanolpiperidine [C] . Yukio Furukawa, Hirotaka Koriki, Daiki Shuto International Conference on Greenhouse Gas Control Technologies . 2017

机译：〜（13）C-NMR研究酸解离常数（PKA）对CO 2吸收和含水链烷醇水溶液再生的影响
5. Amino acids under hydrothermal conditions: Apparent molar volumes, apparent molar heat capacities, and acid /base dissociation constants for aqueous alpha-alanine, beta-alanine, glycine, and proline at temperatures from 25 to 250°C and pressures up to 30.0 MPa. [D] . Clarke, Rodney George Francis. 2000

机译：水热条件下的氨基酸：在25至250°C的温度和最高30.0 MPa的压力下，水性α-丙氨酸，β-丙氨酸，甘氨酸和脯氨酸的表观摩尔体积，表观摩尔热容量和酸/碱解离常数。
6. Preformulation Studies of Zidovudine Derivatives: Acid Dissociation Constants Differential Scanning Calorimetry Thermogravimetry X-Ray Powder Diffractometry and Aqueous Stability Studies [O] . Mónica A. Raviolo, Margarita C. Briñón 2011

机译：齐多夫定衍生物的预配制研究：酸解离常数差示扫描量热法热重法X射线粉末衍射法和水稳定性研究
7. Reply to Comment on the Thermodynamic Dissociation Constant of the Bisulfate Ion from Raman and Ion Interaction Modeling Studies of Aqueous Sulfuric Acid at Low Temperatures [O] . -1

机译：回复对低温下含水硫酸水溶液和离子相互作用研究的二硫酸盐离子热力解离常数的回答
8. Thermodynamics of aqueous sodium sulfate from the temperatures 273 K to 373 K and mixtures of aqueous sodium sulfate and sulfuric acid at 298.15 K [R] . Hovey, J. K., Pitzer, K. S., Rard, J. A. 1991

机译：硫酸钠水溶液的热力学温度为273 K至373 K，硫酸钠和硫酸水溶液的混合物温度为298.15 K

Reply to 'Comment on the 'Thermodynamic Dissociation Constant of the Bisulfate Ion from Raman and Ion Interaction Modeling Studies of Aqueous Sulfuric Acid at Low Temperatures''

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