D-5h C-50 fullerene: A building block for oligomers and solids?

Zhechkov L; Heine T; Seifert G

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D-5h C-50 fullerene: A building block for oligomers and solids?

机译：D-5h C-50富勒烯：低聚物和固体的基础材料？

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The particular stability of recently synthesized C50Cl10 cage is discussed by means of its topology: the underlying C-50 cage consists of two corannulene frameworks which are connected by five C-2 units. C50X10 is another lower fullerene which has not been found experimentally in its bare form. Oligomerization and polymerization of C-50 and C50Hx are investigated. A minimum energy pathway to a D-5h(C-50)(6)H-40 structure is found. C-50 is a candidate structure to form oligomers and fullerides. The preferred bridging positions and the 5-fold symmetry suggest the formation of irregular polymers and oligomers.

机译：通过其拓扑结构讨论了最近合成的C50Cl10笼子的特殊稳定性：下面的C-50笼子由两个Corannulene骨架组成，它们通过五个C-2单元连接。 C50X10是另一种较低的富勒烯，在实验中未以裸露形式发现。研究了C-50和C50Hx的低聚和聚合反应。找到了D-5h（C-50）（6）H-40结构的最小能量路径。 C-50是形成低聚物和富勒酸酯的候选结构。优选的桥接位置和5倍对称性表明形成不规则的聚合物和低聚物。

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《The journal of physical chemistry, A. Molecules, spectroscopy, kinetics, environment, & general theory》 |2004年第52期|共7页
作者
Zhechkov L; Heine T; Seifert G;
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正文语种 eng
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SMALLEST FULLERENE; C-36; CARBON; STABILITY; CAGES; DIMER; C-70; C-60; SPECTROSCOPY; C50CL10;

机译：最小的富勒烯;C-36;碳;稳定性;笼子;二聚体;C-70;C-60;光谱学;C50CL10;

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1. D-5h C-50 fullerene: A building block for oligomers and solids? [J] . Zhechkov L, Heine T, Seifert G The journal of physical chemistry, A. Molecules, spectroscopy, kinetics, environment, & general theory . 2004,第52期

机译：D-5h C-50富勒烯：低聚物和固体的基础材料？
2. C_(36), a hexavalent building block for fullerene compounds and solids [J] . P. W. Fowler, T. Heine, K. M. Rogers, Chemical Physics Letters . 1999,第3a4期

机译：C_（36），用于富勒烯化合物和固体的六价结构单元
3. Bisaziridine tetracarboxylates as building blocks in the stereoselective synthesis of C_(60)-fullerene diads and dumbbell-like bis-C _(60)-fullerene triads [J] . Konev A.S., Khlebnikov A.F., Frauendorf H. The Journal of Organic Chemistry . 2011,第15期

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5. Syntheses of building blocks for organic materials: Spin-labeled nucleosides and thiophene-based oligomers. [D] . Das, Kausik. 2007

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6. Fullerene Building Blocks with Tailor‐Made Solubility and New Insights into Their Hierarchical Self‐Assembly [O] . Dr. M. Eugenia Pérez‐Ojeda, Isabell Wabra, Dr. Christoph Böttcher, -1

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D-5h C-50 fullerene: A building block for oligomers and solids?

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