HI Photofragmentation Revisited.Comment on 'Probing Excited Electronic States Using Vibrationally Mediated Photolysis: Application to Hydrogen Iodide'

Aleksey B.Alekseyev; Daria B.Kokh; Robert J.Buenker

首页> 外文期刊>The journal of physical chemistry, A. Molecules, spectroscopy, kinetics, environment, & general theory >HI Photofragmentation Revisited.Comment on 'Probing Excited Electronic States Using Vibrationally Mediated Photolysis: Application to Hydrogen Iodide'

【24h】

HI Photofragmentation Revisited.Comment on 'Probing Excited Electronic States Using Vibrationally Mediated Photolysis: Application to Hydrogen Iodide'

机译：HI HI碎裂。有关“使用振动介导的光解探测激发的电子态：在碘化氢中的应用”的评论

获取原文

获取原文并翻译 | 示例

掌桥外文数据库（机构版） >>

开具论文收录证明 >>

文献代查 >>

页面导航

摘要
著录项
相似文献
相关主题

摘要

In our recent studies,we have performed a comprehensive theoretical analysis of hydrogen iodide photodissociation in its first absorption band (A band).This band is characterized by a broad featureless absorption spectrum that is formed from transitions to the A~III,a~3II_0~+,and a~3II_1 states.Absorption in the A band leads to prompt HI dissociation into two possible channels H(~2S) + I(~2P~°_(3/2)),I~*(~2P~°_(1/2)).Determination of the branching ratio for these two channels as well as of the role each state plays in the fragmentation process is of great importance not only for HI but also for a much broader class of halide molecules for which HI serves as a prototype system.

机译：在最近的研究中，我们对碘化氢在其第一个吸收带（A带）中的光解离进行了全面的理论分析。该带的特征在于从跃迁到A〜III，a〜3II_0形成的宽广的无特征吸收光谱〜+和a〜3II_1状态.A波段的吸收导致HI迅速分解为两个可能的通道H（〜2S）+ I（〜2P〜°_（3/2）），I〜*（〜2P〜 °_（1/2））。确定这两个通道的分支比以及每个状态在断裂过程中所起的作用不仅对于HI而言，而且对于范围更广的卤化物分子都非常重要。 HI作为原型系统。

著录项

来源
《The journal of physical chemistry, A. Molecules, spectroscopy, kinetics, environment, & general theory》 |2005年第13期|共3页
作者
Aleksey B.Alekseyev; Daria B.Kokh; Robert J.Buenker;
展开▼
作者单位

展开▼
收录信息
原文格式 PDF
正文语种 eng
中图分类
关键词

相似文献

外文文献
中文文献
专利

1. HI Photofragmentation Revisited.Comment on "Probing Excited Electronic States Using Vibrationally Mediated Photolysis: Application to Hydrogen Iodide" [J] . Aleksey B.Alekseyev, Daria B.Kokh, Robert J.Buenker The journal of physical chemistry, A. Molecules, spectroscopy, kinetics, environment, & general theory . 2005,第13期

机译：HI HI碎裂。有关“使用振动介导的光解探测激发的电子态：在碘化氢中的应用”的评论
2. Model of daytime emissions of electronically-vibrationally excited products of O_3 and O_2 photolysis: application to ozone retrieval [J] . V. A. Yankovsky, R. O. Manuilova Annales Geophysicae . 2006,第11期

机译：O_3和O_2光解的电子振动激发产物白天排放模型：在臭氧回收中的应用
3. Doppler line shapes in the photolysis of laser excited, aligned molecules: Application to the vibrationally mediated photodissociation of HN_3 [J] . Rhett James Barnes, Amitabha Sinha, Paul J. Dagdigian, The Journal of Chemical Physics . 1999,第1期

机译：多普勒线形状在激光激发的对准分子的光解中：在HN_3的振动介导的光解离中的应用
4. Vibrational Dynamics of the CN Stretching in the Electronically Excited State by UV and Visible-Pump and Infrared-Probe Spectroscopy [C] . Sho Hiraoka, Kaoru Ohta, Keisuke Tominaga International Conference on Ultrafast Phenomena . 2015

机译：紫外，可见泵和红外探针光谱在电子激发态下CN的振动动力学
5. Vibrational dynamics of excited states probed by fs/ps CARS: Simulations and applications to ultrafast charge transfer dynamics. [D] . Prince, Beth Marie. 2008

机译：fs / ps CARS探测的激发态的振动动力学：超快电荷转移动力学的仿真和应用。
6. Rotational and vibrational dynamics in the excited electronic state of deprotonated and protonated fluorescein studied by time-resolved photofragmentation in an ion trap [O] . Dimitri Imanbaew, Maxim F. Gelin, Christoph Riehn 2016

机译：通过离子阱中的时间分辨光碎裂研究了去质子化和质子化荧光素在激发电子状态下的旋转和振动动力学
7. Model of daytime emissions of electronically-vibrationally excited products of O3 and O2 photolysis: application to ozone retrieval [O] . Yankovsky V. A., Manuilova R. O. 2006

机译：O3和O2光解的电子振动激发产物白天排放模型：在臭氧回收中的应用

HI Photofragmentation Revisited.Comment on 'Probing Excited Electronic States Using Vibrationally Mediated Photolysis: Application to Hydrogen Iodide'

摘要

著录项

相似文献

相关主题

期刊订阅