On the use of ligand field parameters in the study of coordinated water molecules in Eu3+ complexes

Albuquerque RQ; Freire RO; Malta OL

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On the use of ligand field parameters in the study of coordinated water molecules in Eu3+ complexes

机译：关于配体场参数在Eu3 +配合物中配位水分子研究中的应用

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A new methodology is proposed by which the number of coordinated water molecules, n, can be estimated in Eu3+ complexes. It is based on a comparison between the theoretical and experimental Stark levels, the former being calculated by assuming that n varies from 0 to 4 and predicting the so-called ligand field parameters, B-q(k). The methodology, initially developed in the study of the Eu(pya)(3)center dot nH(2)O complex, has been applied successfully to beta-diketonate complexes of Eu3+, for which crystallographic and luminescence data are available.

机译：提出了一种新的方法，据此可以估算Eu3 +配合物中配位水分子的数量n。它基于理论和实验Stark水平之间的比较，前者是通过假设n从0到4变化并预测所谓的配体场参数B-q（k）来计算的。该方法最初是在Eu（pya）（3）中心点nH（2）O络合物的研究中开发的，现已成功应用于Eu3 +的β-二酮酸酯络合物，该晶体的晶体学和发光数据均可用。

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《The journal of physical chemistry, A. Molecules, spectroscopy, kinetics, environment, & general theory》 |2005年第20期|共4页
作者
Albuquerque RQ; Freire RO; Malta OL;
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正文语种 eng
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RARE-EARTH IONS; SPARKLE MODEL; SPECTROSCOPIC PROPERTIES; OVERLAP POLARIZABILITY; EUROPIUM COMPLEXES; CRYSTAL-STRUCTURE; AM1 CALCULATION; LUMINESCENCE; COVALENCY; EU(III);

机译：稀土离子;闪散模型;光谱性质;重叠极化率;EUR络合物;晶体结构;AM1计算;发光度;介电常数;EU（III）;

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1. On the use of ligand field parameters in the study of coordinated water molecules in Eu3+ complexes [J] . Albuquerque RQ, Freire RO, Malta OL The journal of physical chemistry, A. Molecules, spectroscopy, kinetics, environment, & general theory . 2005,第20期

机译：关于配体场参数在Eu3 +配合物中配位水分子研究中的应用
2. Water-soluble Tb3+ and Eu3+ complexes based on task-specific ionic liquid ligands and their application in luminescent poly(vinyl alcohol)films [J] . Li Qing-Feng, Yue Dan, Ge Gen-Wu, Dalton transactions: An international journal of inorganic chemistry . 2015,第38期

机译：基于特定任务离子液体配体的水溶性Tb3 +和Eu3 +配合物及其在发光聚乙烯醇薄膜中的应用
3. Macrocyclic lanthanide complexes as artificial nucleases and ribonucleases: Effects of pH, metal ionic radii, number of coordinated water molecules, charge, and concentrations of the metal complexes [J] . Chang CA, Wu BH, Kuan BY Inorganic Chemistry: A Research Journal that Includes Bioinorganic, Catalytic, Organometallic, Solid-State, and Synthetic Chemistry and Reaction Dynamics . 2005,第19期

机译：大环镧系元素络合物作为人工核酸酶和核糖核酸酶：pH，金属离子半径，配位水分子数，电荷和金属络合物浓度的影响
4. Effect of Structure of Polymeric Nickel Complexes with Salen-Type Ligands on The Stability in Solutions of Water-Containing Electrolytes and The Charge Transfer Parameters [C] . E. V. Alekseeva, M. V. Novogilova, V. A. Ershov International Conference on Advanced Batteries, Accumulators and Fuel Cells . 2018

机译：聚合物镍络合物与盐型配体结构对含水电解质溶液稳定性的影响及电荷转移参数
5. Photoluminescence, Dual-donor Energy Transfer and Single X-ray Crystallographic Studies of Eu3+ and Tb3+ complexes with pyridines and triazaphosphaadamantane oxide (TPAO) ligands. [D] . Forcha, Derick Akaju. 2013

机译：Eu3 +和Tb3 +配合物与吡啶和三氮杂磷金刚烷氧化物（TPAO）配体的光致发光，双供体能量转移和单X射线晶体学研究。
6. Transition Metal Complexes Coordinated by Water Soluble Phosphane Ligands: How Cyclodextrins Can Alter the Coordination Sphere? [O] . Michel Ferreira, Hervé Bricout, Sébastien Tilloy, 2017

机译：水溶性磷配体配位的过渡金属配合物：环糊精如何改变配位域？
7. On the Use of Ligand Field Parameters in the Study of Coordinated Water Molecules in Eu3+ Complexes [O] . -1

机译：在EU3 +络合物中配位水分子研究中的使用
8. LIGAND FIELD PARAMETERS FOR Eu3+ IN REVO4 (RE=Gd, Y, AND Lu) [R] . G. GRENET, M. KIBLER, C. LINARES 1977

机译：Eu3 + IN REVO4的配体场参数（RE = Gd，Y和Lu）

On the use of ligand field parameters in the study of coordinated water molecules in Eu3+ complexes

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