The Conversion of Methane to Methanol:A Reaction Catalyzed by I~+ or I_2~+?

Gustavo E.Davico

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The Conversion of Methane to Methanol:A Reaction Catalyzed by I~+ or I_2~+?

机译：甲烷转化为甲醇：I〜+或I_2〜+？催化的反应

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The gas-phase reactions of I~+ and I_2~+ with methane were studied to determine which species is involved in the oxidation of methane to methyl sulfate,an intermediate in the production of methanol.We found that while I~+ reacts readily with methane,I_2~+ does not react in our experimental reaction conditions.Reaction products and rate constants are measured and reported.In addition,ab initio calculations were carried out to further understand the reaction mechanism.A revised mechanism of catalysis is proposed which is in excellent agreement with available experimental data and our theoretical computations.

机译：研究了I〜+和I_2〜+与甲烷的气相反应，确定了甲烷氧化为甲醇生产中的中间体甲烷氧化为甲基的过程。甲烷，I_2〜+在我们的实验反应条件下不发生反应。测量并报告了反应产物和速率常数。此外，从头开始计算以进一步了解反应机理。提出了一种改进的催化机理与现有的实验数据和我们的理论计算非常吻合。

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《The journal of physical chemistry, A. Molecules, spectroscopy, kinetics, environment, & general theory》 |2005年第15期|共5页
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Gustavo E.Davico;
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1. The Conversion of Methane to Methanol:A Reaction Catalyzed by I~+ or I_2~+? [J] . Gustavo E.Davico The journal of physical chemistry, A. Molecules, spectroscopy, kinetics, environment, & general theory . 2005,第15期

机译：甲烷转化为甲醇：I〜+或I_2〜+？催化的反应
2. Theoretical Studies on the Mechanisms of the Methane -> Methanol Conversion Reaction Catalyzed by Methane Monooxygenase: O-Side vs N-Side Mechanisms [J] . Harold Basch, Koichi Mogi, Keiji Morokuma, The journal of physical chemistry, A. Molecules, spectroscopy, kinetics, environment, & general theory . 2001,第14期

机译：甲烷单加氧酶催化甲烷→甲醇转化反应机理的理论研究：O-侧与N-侧机理
3. One-pot tandem reactions for direct conversion of thiols and disulfides to sulfonic esters, alcohols to bis(indolyl)methanes and synthesis of pyrroles catalyzed by N-chloro reagents [J] . Veisi H., Ataee M., Fatolahi L., Letters in organic chemistry . 2013,第2期

机译：一锅串联反应，将硫醇和二硫化物直接转化为磺酸酯，将醇转化为双（吲哚基）甲烷，并通过N-氯试剂催化合成吡咯
4. Identification of the Reaction Pathway and Active Site for the Catalytic Conversion of Methane to Methanol over Copper-Exchanged Zeolites [C] . Kimberly Dinh, Mark Sullivan, Pedro Serna Natural Gas Conversion Symposium . 2019

机译：在铜交换沸石上鉴定甲烷催化转化对甲醇的反应途径和活性位点
5. Electric field-enhanced catalytic conversion of methane: An experimental study on the effects of corona discharge on methane reactions. [D] . Marafee, Abdulathim M. J. 1996

机译：电场增强的甲烷催化转化：电晕放电对甲烷反应影响的实验研究。
6. RuCl3·3H2O Catalyzed Reactions: Facile Synthesis of Bis(indolyl)methanes under Mild Conditions [O] . Hong-En Qu, Chen Xiao, Ning Wang, 2011

机译：RuCl3·3H2O催化反应：在温和条件下轻松合成双（吲哚基）甲烷
7. Conversion of Methane to Methanol: A Reaction Catalyzed by I+ or I2+? [O] . -1

机译：将甲烷转化为甲醇：通过I +或I2 +催化的反应？
8. Preparation and Characterization of Ligand Types Intermediate in the Metal Catalyzed Conversion of Coal to Methane, Methanol, and Higher Alkanes and Alcohols. Final Progress Report, September 1, 1978-June 30, 1982 [R] . Truhan, J. J., Aceves, S. C., McCright, R. D. 1982

机译：金属催化煤转化为甲烷，甲醇和高级烷烃和醇的中间体配体类型的制备和表征。最终进展报告，1978年9月1日至1982年6月30日

The Conversion of Methane to Methanol:A Reaction Catalyzed by I~+ or I_2~+?

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